Synthesis and Spectral Properties of Ni(II), Pd(II), Pt(II), and Pt(IV) Tetraphenyltetrabenzoporphyrinates
- Авторы: Chizhova N.V.1, Mal’tseva O.V.1, Kumeev R.S.1, Mamardashvili N.Z.1
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Учреждения:
- Krestov Institute of Solution Chemistry
- Выпуск: Том 63, № 5 (2018)
- Страницы: 682-686
- Раздел: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/168706
- DOI: https://doi.org/10.1134/S0036023618050200
- ID: 168706
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Аннотация
Complexation reactions of 5,10,15,20-tetraphenyltetrabenzoporphyrin and transmetallation of its cadmium complex with nickel(II) acetate, Ni(II), Pd(II), and Pt(II) chlorides in dimethylformamide and phenol have been studied. The corresponding Ni(II), Pd(II), and Pt(II) porphyrinates have been synthesized. PtIVBr2 porphyrinate has been obtained by the treatment of Pt(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate with bromine in chloroform. The obtained compounds have been characterized by elemental analysis, electronic absorption and 1H NMR spectroscopy and mass spectrometry.
Об авторах
N. Chizhova
Krestov Institute of Solution Chemistry
Автор, ответственный за переписку.
Email: nvc@isc-ras.ru
Россия, Ivanovo, 153045
O. Mal’tseva
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Россия, Ivanovo, 153045
R. Kumeev
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Россия, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Россия, Ivanovo, 153045
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