Selective hydrothermal microwave synthesis of various manganese dioxide polymorphs


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Hydrothermal microwave treatment of mixed solutions of potassium permanganate and hexamethylenetetramine within the pH range 0.5–6.9, resulted in various polymorphs of nanocrystalline manganese dioxide: α-MnO2 (cryptomelane), γ-MnO2 (nsutite), β-MnO2 (pyrolusite), and δ-MnO2 (birnessite). The pH values of the medium at which single-phase samples form were determined.

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R. Korotkov

Lomonosov Moscow State University

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俄罗斯联邦, Vorob’evy gory, Moscow, 119992

A. Baranchikov

Lomonosov Moscow State University; Kurnakov Institute of General and Inorganic Chemistry

Email: neocube007@yandex.ru
俄罗斯联邦, Vorob’evy gory, Moscow, 119992; Leninskii pr. 31, Moscow, 119991

O. Boytsova

Lomonosov Moscow State University; Kurnakov Institute of General and Inorganic Chemistry

Email: neocube007@yandex.ru
俄罗斯联邦, Vorob’evy gory, Moscow, 119992; Leninskii pr. 31, Moscow, 119991

A. Goldt

Lomonosov Moscow State University; Kurnakov Institute of General and Inorganic Chemistry

Email: neocube007@yandex.ru
俄罗斯联邦, Vorob’evy gory, Moscow, 119992; Leninskii pr. 31, Moscow, 119991

S. Kurzeev

Lomonosov Moscow State University

Email: neocube007@yandex.ru
俄罗斯联邦, Vorob’evy gory, Moscow, 119992

V. Ivanov

Kurnakov Institute of General and Inorganic Chemistry; National Research Tomsk State University

Email: neocube007@yandex.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; pr. Lenina 36, Tomsk, 634050

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