Мақаланы E-mail арқылы жіберу Study of isotope effect upon lithium iodide complexation with benzo-15-crown-5 in water–chloroform extraction system
- Авторлар: Shokurova N.A.1, Demina L.I.1,2, Zhilov V.I.1,2, Demin S.V.1,2, Tsivadze A.Y.1
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Мекемелер:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Шығарылым: Том 61, № 6 (2016)
- Беттер: 787-790
- Бөлім: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/166563
- DOI: https://doi.org/10.1134/S0036023616060176
- ID: 166563
Дәйексөз келтіру
Ашық рұқсат
Рұқсат берілді
Тек жазылушылар үшін
Аннотация
Extraction characteristics of chloroform–water system in lithium iodide extraction with benzo-15-crown-5 (B15C5) were studied. The complexation of the crown ether with LiI in organic phase was shown by IR spectroscopy. Isotope effect multiplication was performed by extraction chromatography technique. The magnitude of isotope separation factor (α) for 6Li-7Li pair was 1.017. The light lithium isotope is concentrated in organic phase.
Авторлар туралы
N. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Ресей, Leninskii pr. 31, Moscow, 119991
L. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
V. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Хат алмасуға жауапты Автор.
Email: zhilov@igic.ras.ru
Ресей, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
S. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Ресей, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Ресей, Leninskii pr. 31, Moscow, 119991
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