Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline


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The reaction products formed in the SO2–L–H2O–O2 systems (L is n-propylamine, n-butylamine, tert-butylamine, n-heptylamine, n-octylamine, aniline) were isolated and identified as “onium” salts [n-C3H7NH3]2SO4, [n-C4H9NH3]2SO4, [t-C4H9NH3]2SO4, [n-C7H15NH3]3SO4(HSO4), [n-C8H17NH3]3SO4(HSO4), and [C6H5NH3]2SO4. The products were characterized by elemental analysis, IR and Raman spectroscopy, mass spectrometry, and thermogravimetry.

Sobre autores

R. Khoma

Physical Chemical Institute for Environment and Human Protection; Odessa Mechnikov National University

Autor responsável pela correspondência
Email: rek@onu.edu.ua
Ucrânia, Odessa, 65082; Odessa, 65082

V. Gel’mbol’dt

Odessa National Medical University

Email: rek@onu.edu.ua
Ucrânia, Odessa, 65082

A. Ennan

Physical Chemical Institute for Environment and Human Protection

Email: rek@onu.edu.ua
Ucrânia, Odessa, 65082

V. Baumer

NTK Institute of Single Crystals

Email: rek@onu.edu.ua
Ucrânia, Kharkiv, 61001

I. Rakipov

Bogatsky Physico-Chemical Institute

Email: rek@onu.edu.ua
Ucrânia, Odessa, 65080

R. Dlubovskii

Physical Chemical Institute for Environment and Human Protection

Email: rek@onu.edu.ua
Ucrânia, Odessa, 65082

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