Phase equilibria in the Cu2S–La2S3–EuS system

Resumo

Phase equilibria in the isothermal (970 K) and polythermal LaCuS₂–EuS, Cu₂S–EuLaCuS₃, LaCuS₂–EuLa₂S₄, and EuLaCuS₃–EuLa₂S₄ sections of the Cu₂S–La₂S₃–EuS system have been studied. EuLaCuS₃ (annealing at 1170 K) is of orthorhombic system, space group Pnma, a = 8.1366(1) Å, b = 4.0586(1) Å, c = 15.9822(2) Å, is isostructural to Ba₂MnS₃, and incongruently melts by the reaction EuLaCuS_3cryst (0.50 EuS; 0.50 LaCuS₂) ↔ 0.22 EuS SS (0.89 EuS; 0.11 LaCuS₂) + 0.78 liq (0.39 EuS; 0.61 LaCuS₂); ΔН = 52 J/g. The Cu₂S–La₂S3–EuS system has been found to contain five major subordinate triangles. At 970 K, tie-lines lie between EuLaCuS₃ and the Cu₂S, EuS, LaCuS₂, and EuLa₂S₄ phases and between the LaCuS₂ phase and the γ-La₂S₃–EuLa2S4 solid solution. Eutectics are formed between LaCuS₂ and EuLaCuS₃ at 26.0 mol % of EuS and T = 1373 K and between EuLaCuS3 and EuLa₂S₄ at 29.0 mol % of EuLa₂S₄ and T = 1533 K.