Email this article Synthesis of a Novel Manganese(III) Porphyrin and Its Catalytic Role in Selective Oxidation of Aromatic Alcohols
- Authors: Niharika Anand 1, Yadava S.1, Chaurasia P.K.2, Bharati S.L.3
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Affiliations:
- Niharika Anand and Sudha Yadava, Department of Chemistry, DDU Gorakhpur University
- Department of Chemistry, LS College, Muzaffarpur
- Department of Chemistry, North Eastern Regional Institute of Science and Technology
- Issue: Vol 64, No 9 (2019)
- Pages: 1101-1104
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169471
- DOI: https://doi.org/10.1134/S003602361909002X
- ID: 169471
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Abstract
A novel azido complex of manganese(III) porphyrin with 1-methylimidazole has been synthesized. This complex can be abbreviated as [MnIII(THMPP)N3(1-MeIm)], where THMPP is 5,10,15,20-tetrakis(4-hydroxy-3-methoxyphenyl)porphine and 1-MeIm is 1-methylimidazole. The complex has been characterized by UV-visible, FT-IR, ESI-MS spectra, elemental analysis, and magnetic susceptibility. The tentative structure has been proposed to be octahedral. The catalytic activity of the complex synthesized has been studied using different oxidants in the selective oxidation of aromatic alcohols to aldehydes. The selectively transformed products have been obtained under room conditions and short time period in high yields.
About the authors
Niharika Anand
Niharika Anand and Sudha Yadava, Department of Chemistry, DDU Gorakhpur University
Email: shashilatachem@gmail.com
India, Gorakhpur, 273009
Sudha Yadava
Niharika Anand and Sudha Yadava, Department of Chemistry, DDU Gorakhpur University
Email: shashilatachem@gmail.com
India, Gorakhpur, 273009
Pankaj Kumar Chaurasia
Department of Chemistry, LS College, Muzaffarpur
Author for correspondence.
Email: pankaj.chaurasia31@gmail.com
India, Bihar, 842001
Shashi Lata Bharati
Department of Chemistry, North Eastern Regional Institute of Science and Technology
Author for correspondence.
Email: shashilatachem@gmail.com
India, Nirjuli, Arunachal Pradesh, 791109
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