Email this article 1,8-Bis[2-(diphenylphosphoryl)phenoxy-4-phenyldiazenyl)]-3,6-dioxaoctane (L): Synthesis and Complexing and Ion-Selective Properties. Crystal and Molecular Structures of L · 0.25H2O and [LiL]I3 · MePh
- Authors: Ivanova I.S.1, Ilyukhin A.B.1, Polyakova I.N.1, Rogacheva Y.I.2, Pyatova E.N.1, Tsebrikova G.S.3, Baulin V.E.2,3, Tsivadze A.Y.3
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Institute of Physiologically Active Substances
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 64, No 2 (2019)
- Pages: 216-224
- Section: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169244
- DOI: https://doi.org/10.1134/S0036023619020098
- ID: 169244
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Abstract
The synthesis, IR and electronic absorption spectra, and ion-selective properties of 1,8-bis[2-(diphenylphosphoryl)phenoxy-4-phenyldiazenyl]-3,6-dioxaoctane (L), a new phosphoryl podand, are described. The crystal structures of L · 0.25H2O and the synthesized complex [LiL]I3 · MePh were characterized by X-ray diffraction. The composition of the plasticized polymeric membrane of a lithium-selective electrode based on L was determined.
About the authors
I. S. Ivanova
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: isivanova@mail.ru
Russian Federation, Moscow, 119991
A. B. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Russian Federation, Moscow, 119991
I. N. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Russian Federation, Moscow, 119991
Yu. I. Rogacheva
Institute of Physiologically Active Substances
Email: isivanova@mail.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
E. N. Pyatova
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
Russian Federation, Moscow, 119991
G. S. Tsebrikova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Moscow, 199991
V. E. Baulin
Institute of Physiologically Active Substances; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432; Moscow, 199991
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
Russian Federation, Moscow, 199991
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