Email this article Thermal Decomposition of Unsaturated Nickel(II) Dicarboxylates
- Authors: Musatova V.Y.1, Drobot D.V.1, Dzhardimalieva G.I.2, Semenov S.A.1
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Affiliations:
- MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
- Institute of Problems of Chemical Physics
- Issue: Vol 63, No 9 (2018)
- Pages: 1217-1224
- Section: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/168989
- DOI: https://doi.org/10.1134/S0036023618090164
- ID: 168989
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Abstract
Thermal decomposition of nickel hydrogen carboxylates (NHCs) of unsaturated dicarboxylic acids has been studied by the TGA/DTA method in combination with DSC analysis and mass spectrometry of gaseous thermolysis products. The temperature ranges of the key stages of the thermal decomposition of NHCs were determined: (1) dehydration, 50–275°C; (2) polymerization of dehydrated carboxylate, 125–360°C; (3) decarboxylation, 290–450°C. A conclusion has been made that these stages can overlap one another and proceed simultaneously.
About the authors
V. Yu. Musatova
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Email: srg.semenov@gmail.com
Russian Federation, Moscow, 119454
D. V. Drobot
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Email: srg.semenov@gmail.com
Russian Federation, Moscow, 119454
G. I. Dzhardimalieva
Institute of Problems of Chemical Physics
Email: srg.semenov@gmail.com
Russian Federation, Chernogolovka, Moscow oblast, 142432
S. A. Semenov
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Author for correspondence.
Email: srg.semenov@gmail.com
Russian Federation, Moscow, 119454
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