Solvothermal Decomposition of α-Co(OH)2@SDS in n-Octanol


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Abstract

The solvothermal decomposition of a hybrid organic–inorganic material based on α-Со(ОН)2 and sodium dodecyl sulfate has been studied in n-octanol at 190°C and the atmospheric pressure. It has been found that the process includes two stages: in the first stage, anhydrous CoCO3 is formed, followed by its topochemical decomposition to form Co3O4. It has been found that products consist of rhombic-shaped particles about 250 nm in size.

About the authors

E. V. Pikurova

Institute of Chemistry and Chemical Technology, Siberian Branch

Author for correspondence.
Email: vitaelen@gmail.com
Russian Federation, Krasnoyarsk, 660036

S. V. Saikova

Siberian Federal University

Email: vitaelen@gmail.com
Russian Federation, Krasnoyarsk, 660041

G. L. Pashkov

Institute of Chemistry and Chemical Technology, Siberian Branch

Email: vitaelen@gmail.com
Russian Federation, Krasnoyarsk, 660036

M. V. Panteleeva

Institute of Chemistry and Chemical Technology, Siberian Branch

Email: vitaelen@gmail.com
Russian Federation, Krasnoyarsk, 660036

Yu. L. Mikhlin

Institute of Chemistry and Chemical Technology, Siberian Branch

Email: vitaelen@gmail.com
Russian Federation, Krasnoyarsk, 660036

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