Email this article Rhenium(VII) extraction with Versatic hydrazides and N',N'-Dialkylhydrazides
- Authors: Batueva T.D.1, Shcherban’ M.G.2
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Affiliations:
- Institute of Technical Chemistry, Ural Branch
- Perm State University
- Issue: Vol 62, No 10 (2017)
- Pages: 1409-1413
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/168119
- DOI: https://doi.org/10.1134/S0036023617100035
- ID: 168119
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Abstract
Rhenium(VII) and molybdenum(VI) extraction with kerosene solutions of α-branched tertiary carboxylic Versatic acids derivatives containing hydrazide C(O)NHNH2 and C(O)NHNCH3)2 fragments instead of carboxyl group has been studied. Optimal extraction conditions have been determined depending on H2SO4, HCl, and extractant concentrations and composition of extracted complexes has been established. The mechanism of extraction and back extraction of perrhenate ion with ammonia solutions has been suggested.
About the authors
T. D. Batueva
Institute of Technical Chemistry, Ural Branch
Author for correspondence.
Email: tdbatueva@mail.ru
Russian Federation, Perm, 614013
M. G. Shcherban’
Perm State University
Email: tdbatueva@mail.ru
Russian Federation, Perm, 614990
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