Synthesis and thermodynamics of lead(II), manganese(II), and cobalt(II) pivalate complexes
- Authors: Dement’ev A.1, Rodyakina S.1,2, Kayumova D.2, Kamkin N.1, Yaryshev N.1, Alikhanyan A.2
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Affiliations:
- Institute of Biology and Chemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 62, No 10 (2017)
- Pages: 1379-1383
- Section: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/168107
- DOI: https://doi.org/10.1134/S0036023617100060
- ID: 168107
Cite item
Abstract
Manganese and cobalt oxopivalates and lead pivalate have been synthesized, mass spectral and thermogravimetric analysis have been performed. Sublimation enthalpies of cobalt and manganese oxopivalates have been determined for the first time, while the sublimation enthalpy of lead pivalate has been found to agree well with literature data. Low sublimation enthalpy, high volatility, and monomolecular composition of gas phase allow one to use these complexes as precursors for preparing oxide films and materials by MOCVD method.
About the authors
A.I. Dement’ev
Institute of Biology and Chemistry
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435
S.N. Rodyakina
Institute of Biology and Chemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435; Moscow, 119991
D.B. Kayumova
Kurnakov Institute of General and Inorganic Chemistry
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991
N.N. Kamkin
Institute of Biology and Chemistry
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435
N.G. Yaryshev
Institute of Biology and Chemistry
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435
A.S. Alikhanyan
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991
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