Synthesis and thermodynamics of lead(II), manganese(II), and cobalt(II) pivalate complexes


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Abstract

Manganese and cobalt oxopivalates and lead pivalate have been synthesized, mass spectral and thermogravimetric analysis have been performed. Sublimation enthalpies of cobalt and manganese oxopivalates have been determined for the first time, while the sublimation enthalpy of lead pivalate has been found to agree well with literature data. Low sublimation enthalpy, high volatility, and monomolecular composition of gas phase allow one to use these complexes as precursors for preparing oxide films and materials by MOCVD method.

About the authors

A.I. Dement’ev

Institute of Biology and Chemistry

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435

S.N. Rodyakina

Institute of Biology and Chemistry; Kurnakov Institute of General and Inorganic Chemistry

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435; Moscow, 119991

D.B. Kayumova

Kurnakov Institute of General and Inorganic Chemistry

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

N.N. Kamkin

Institute of Biology and Chemistry

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435

N.G. Yaryshev

Institute of Biology and Chemistry

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119435

A.S. Alikhanyan

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

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