Use of carboxylic acids in the extractive conversion of rare earth chlorides into nitrates


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The main characteristics of extraction system for the conversion of total rare earth chlorides into nitrates with the use of higher isomeric carboxylic acids as extractants have been determined. Laboratory simulation of the process shows that two simplest manipulations: extraction and back extraction, allows conversion of total rare earth chlorides into nitrates with their simultaneous preconcentration by factor larger 40 without evaporation stage. These results can be further used in practice, for example, in the processes of extractive separation of rare earth elements.

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G. Kostikova

Frumkin Institute of Physical Chemistry and Electrochemistry

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Email: galyna_k@mail.ru
俄罗斯联邦, Moscow, 119071

V. Zhilov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: galyna_k@mail.ru
俄罗斯联邦, Moscow, 119071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: galyna_k@mail.ru
俄罗斯联邦, Moscow, 119071

E. Sal’nikova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: galyna_k@mail.ru
俄罗斯联邦, Moscow, 119071

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