Association of bromate ion in nonaqueous solutions of alkali metal salts

详细

Manifestations of ion association of lithium cation with BrO₃^- ion in the vibrational spectrum have been studied by IR spectroscopy. The microstructure of the bromate ion with lithium cation in a contact ion pair in an aprotic solvent has been determined by the density functional theory method in the B3LYP/cc-pVTZ approximation, and the vibrational spectrum of coordinated bromate ion has been calculated.