Email this article Tetra(hexamethylphosphoric triamide) solvate with ammonium tetrakis(isothiocyanato)diamminechromate(III): Synthesis and crystal structure
- Authors: Bobrovnikova A.A.1, Peresypkina E.V.2,3, Virovets A.V.2,3, Cherkasova T.G.1, Tatarinova E.S.1
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Affiliations:
- Kuzbass State Technical University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- National Research Novosibirsk State University
- Issue: Vol 62, No 3 (2017)
- Pages: 355-360
- Section: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/167471
- DOI: https://doi.org/10.1134/S0036023617030056
- ID: 167471
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Abstract
Ammonium tetrakis(isothiocyanato)diamminechromate(III) crystalline solvate (NH4)[Cr(NH3)2(NCS)4] ∙ 4((CH3)2N)3PO (I) has been synthesized and structurally characterized. Crystals of solvate I are tetragonal, space group P\(\overline{4}\)21c, a = 15.8594(3) Å, c = 11.1675(2) Ǻ, V = 2808.86(9) Ǻ3, Z = 2, ρcalcd = 1.245 g/cm3, ρmeas = 1.21 g/cm3. Cations, solvate molecules, and anions form chains in a crystal by means of intermolecular hydrogen bonds.
About the authors
A. A. Bobrovnikova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. V. Peresypkina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
A. V. Virovets
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
T. G. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. S. Tatarinova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
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