Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties

G. M. Mamardashvili; N. V. Chizhova; E. Yu. Kaigorodova; N. Zh. Mamardashvili

doi:10.1134/S0036023617030123

Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties

Authors: Mamardashvili G.M.¹, Chizhova N.V.¹, Kaigorodova E.Y.¹, Mamardashvili N.Z.¹
Affiliations:
1. Krestov Institute of Solution Chemistry
Issue: Vol 62, No 3 (2017)
Pages: 301-308
Section: Coordination Compounds
URL: https://journals.rcsi.science/0036-0236/article/view/167439
DOI: https://doi.org/10.1134/S0036023617030123
ID: 167439

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Abstract

Comparison of tetrabenzoporphyrin complexation reactions and transmetalation of cadmium(II) tetrabenzoporphyrinate with cobalt(II) acetate and chloride in dimethylformamide (DMF) has been carried out Cobalt(III) tetrabenzoporphyrinate has been prepared and identified. Acido ligands displacement in Co(III) tetrabenzoporphyrinate by pyridine, imidazole, and quinuclidine molecules has been studied.