Metal exchange of Cd(II) octaphenyltetraazaporphyrin with d-metal salts in organic solvents


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Abstract

The metal exchange of Cd(II) octaphenyltetraazaporphyrin with CoCl2 and MnCl2 was studied by spectrophotometry in DMF and DMSO. The kinetic parameters of the metal exchange were determined. A possible stoichiometric reaction mechanism was proposed.

About the authors

S. V. Zvezdina

Krestov Institute of Solution Chemistry

Author for correspondence.
Email: svvr@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

N. Zh. Mamardashvili

Krestov Institute of Solution Chemistry

Email: svvr@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

O. I. Koifman

Krestov Institute of Solution Chemistry; Institute of Chemistry of Macroheterocyclic Compounds

Email: svvr@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045; Ivanovo

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