Email this article Lithium isotope effects in extraction of lithium chloride by benzo-15-crown-5 in the 1,1,7-trihydrododecafluoroheptanol–water system
- Authors: Demin S.V.1, Zhilov V.I.2, Tsivadze A.Y.2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 61, No 1 (2016)
- Pages: 119-122
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0236/article/view/167089
- DOI: https://doi.org/10.1134/S0036023616010071
- ID: 167089
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Abstract
The extraction characteristics of the 1,1,7-trihydrododecafluoroheptanol water system have been studied for lithium chloride as the salt to be extracted and benzo-15-crown-5 as the extracting agent, as well as blank extraction of lithium chloride in this system. Single-stage lithium isotope separation factors (a) have been measured at various lithium chloride concentrations in water, and the isotope effect has been multiplied by extraction chromatography. The value of a for the Li6–Li7 pair was 1.024. The light lithium isotope is concentrated in the organic phase.
About the authors
S. V. Demin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
V. I. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: zhilov@igic.ras.ru
Russian Federation, Moscow
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow
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