Sulfated alumina aerogel-based superacid catalysts for 1-hexene oligomerization


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Al2O3 aerogel samples were synthesized by supercritical drying in two different media: isopropanol and methyl tert-butyl ether. After sulfation in a SO2Cl2 vapor, the aerogel acquired superacid properties (–12.4 ≤ H0 ≤–11.99) and efficiently catalyzed 1-hexene oligomerization and dimerization.

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S. Lermontov

Institute of Physiologically Active Compounds

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Email: lermontov52@yandex.ru
俄罗斯联邦, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432

L. Yurkova

Institute of Physiologically Active Compounds

Email: lermontov52@yandex.ru
俄罗斯联邦, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432

E. Straumal

Institute of Physiologically Active Compounds

Email: lermontov52@yandex.ru
俄罗斯联邦, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432

A. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry

Email: lermontov52@yandex.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

I. Shunina

Institute of Problems of Chemical Physics

Email: lermontov52@yandex.ru
俄罗斯联邦, Moscow oblast, 142432

V. Ivanov

Kurnakov Institute of General and Inorganic Chemistry

Email: lermontov52@yandex.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

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