Phase equilibria in the NaCl–NaBO2–Na2CO3–KCl quaternary system


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Abstract

The phase diagrams of the ternary systems NaCl–NaBO2–KCl, NaCl–KCl–Na2CO3, and KCl–NaBO2–Na2CO3 and the quaternary system NaCl–NaBO2–Na2CO3–KCl were studied by the calculation–experimental method and differential thermal analysis. Analytical models of phase equilibria were obtained, and the coordinates of ternary eutectics and a quaternary eutectic. It was shown that low-melting eutectic melts can be used as media for synthesizing oxide tungsten bronzes.

About the authors

Zh. A. Kochkarov

Kabardino-Balkarian State University

Author for correspondence.
Email: chemest2@rambler.ru
Russian Federation, Nalchik, 360004

R. A. Zhizhuev

Kabardino-Balkarian State University

Email: chemest2@rambler.ru
Russian Federation, Nalchik, 360004

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