Email this article Formation of 1-D polymer in recrystallization of the adduct Mn[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 from acetonitrile
- Authors: Grineva A.A.1, Ageshina A.A.1, Uvarova M.A.1, Nefedov S.E.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 61, No 9 (2016)
- Pages: 1092-1096
- Section: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/166741
- DOI: https://doi.org/10.1134/S0036023616090060
- ID: 166741
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Abstract
It was found that the recrystallization of the adduct Mn[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 from hot acetonitrile in the presence of benzene produces polymer [μ-(OOCC5H4)Mn(CO)3]4[μ-η2-(OOCC5H4)Mn(CO)3]2(NCMe)2(OH2)2([μ-η2-(OOCC5H4)Mn(CO)3]2)[μ-(OOCC5H4)Mn(CO)3]4[μ-η2-(OOCC5H4)Mn(CO)3]2(OH2)2n. The obtained polymer was characterized by X-ray diffraction analysis.
About the authors
A. A. Grineva
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Leninskii pr. 65, Moscow, 119991
A. A. Ageshina
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Leninskii pr. 65, Moscow, 119991
M. A. Uvarova
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Leninskii pr. 65, Moscow, 119991
S. E. Nefedov
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: snef@igic.ras.ru
Russian Federation, Leninskii pr. 65, Moscow, 119991
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