Qualitative Assessment of the Contribution of Various Components to Cu(II) Adsorption by Alluvial Soddy-Gley Soil

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Abstract

Using the method of sequential removal of various types of sorption surfaces, a qualitative assessment of the contribution of organic matter, non-silicate iron compounds, and clay minerals to the adsorption of Cu(II) by alluvial soddy-gley soil was carried out under the conditions of laboratory equilibrium experiments. It has been established that the contribution of each of the components is determined both by the ability to form surface inner-sphere complexes at pH-dependent positions, and by the availability of sorption centers in the places of localization of a constant charge of clay minerals. In the AY horizon, the main components sorbing Cu(II) are organic matter and nonsilicate iron compounds, while in the ABg and BDg horizons, clay minerals make the main contribution to Cu(II) adsorption under the experimental conditions. The main mechanism of Cu(II) adsorption in the AY horizon is ion exchange with H+ on functional groups of organic matter and surface hydroxyls of nonsilicate iron compounds. In the underlying horizons, Cu(II) is mainly sorbed as a result of ion exchange with cations that compensate for the constant charge of the crystal lattices of clay minerals. Soil treatment with 10% H2O2 and the Mehra-Jackson reagent leads to a change in the surface area, quality and quantity of sorption centers, and to the transformation of the crystal lattices of clay minerals. These changes should be taken into account when assessing the contribution of soil components to the sorption of metal ions.

About the authors

M. I. Pyatova

Lomonosov Moscow State University

Email: itolp@soil.msu.ru
Russia, 119991, Moscow

I. I. Tolpeshta

Lomonosov Moscow State University

Author for correspondence.
Email: itolp@soil.msu.ru
Russia, 119991, Moscow

Yu. G. Izosimova

Lomonosov Moscow State University

Email: itolp@soil.msu.ru
Russia, 119991, Moscow

М. М. Karpukhin

Lomonosov Moscow State University

Email: itolp@soil.msu.ru
Russia, 119991, Moscow

N. Yu. Barsova

Lomonosov Moscow State University

Email: itolp@soil.msu.ru
Russia, 119991, Moscow

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