卷 119, 编号 4 (2018)

The influence of the interface structure on the magnetoresistive properties of Co/Cu superlattices has been studied using the techniques of nuclear magnetic resonance and X-ray reflectivity. It has been found that the roughness of interfaces and the number of cobalt atoms involved in their formation increase with annealing temperature, while the fraction of highly perfect interfaces decreases at higher temperatures. It has been demonstrated that the probability of the scattering of conduction electrons by interfaces increases with the width of these boundaries.

A comparative analysis of the magnetic properties and specific features of the giant magnetoimpedance has been carried out for amorphous rapidly quenched wires with a composition of (Co_0.94Fe_0.06)_72.5Si_12.5B₁₅ in the initial state and after the deposition of a carbon coating. The deposition of the defective graphene-like carbon layer was carried out under normal conditions during the exposure in toluene (methylbenzene). The method of the energy-dispersive X-ray spectroscopy made it possible to reliably show that after the modification in toluene, the carbon content on the surface significantly exceeds the natural amount of carbon. The deposition of the carbon coating induced changes in the distribution of the initial quenching stresses in the near-surface layer of amorphous wires. A comparative analysis of the magnetic and magnetoimpedance properties of the samples before and after exposure in the aromatic solvent confirms the occurrence of changes in the effective magnetic anisotropy as a result of this surface treatment.

The interfacial microstructure and resistivity of cold-drawn and annealed thin layers copper cladding steel (CCS) wires have been systematically investigated by the methods of scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and resistivity testing. The results showed that the Cu and Fe atoms near interface diffused into each other matrixes. The Fe atoms diffused into Cu matrixes and formed a solid solution. The mechanism of solid solution is of substitution type. When the quantity of Fe atoms exceeds the maximum solubility, the supersaturated solid solution would form Fe clusters and decompose into base Cu and α-Fe precipitated phases under certain conditions. A few of α-Fe precipitates was observed in the copper near Cu/Fe interfaces of cold-drawn CCS wires, with 1–5 nm in size. A number of α-Fe precipitates of 1–20 nm in size can be detected in copper near Cu/Fe interfaces of CCS wires annealed at 850°C. When annealing temperature was less than 750°C, the resistivity of CCS wires annealed was lower than that of cold-drawn CCS wires. However, when annealing temperature was above 750°C, the resistivity of CCS wires was greater than that of cold-drawn CCS wires and increased with rising the annealing temperature. The relationship between nanoscale α-Fe precipitation and resistivity of CCS wires has been well discussed.

In this work, the formation of a packet structure composed of colonies of lamellar plates separated by twin boundary {101}_fct in In–4.5 wt % Cd alloy upon cooling below the fcc → fct martensitic transition temperature has been shown using the methods of metallography, X-ray diffraction, transmission electron microscopy, and EBSD analysis. Two neighboring lamellae differ from each other by the direction of their tetragonality axes. Using ЕВSD analysis, it has been established that neighboring packets always contain three types of tetragonal martensite lamellae, which are in twin positions and differ from each other by the direction of their tetragonality axes. In turn, each martensite lamella consists of a set of smaller lamellae, which are in twin positions. After the cycle of fct → fcc → fct transitions, the alloy recrystallizes with a decrease in the grain size by several times compared with the initial structure such that the size of packets and the length and width of martensitic lamellae in a packet correlate with a change in the size of an alloy grain.

Structural and microstructural changes that arise in the course of the heat treatment of Cr–Ni–Mo austenitic stainless steels with different concentrations of titanium and phosphorus have been studied. It has been found that the alloying with phosphorus decreases the lattice parameter of these steels. The phosphorus contribution to this effect is 0.015 ± 0.002 Å/at %. Aging at a temperature of 670 K for about 20 h leads to the precipitation of dispersed needle-like particles, which are most likely to be iron phosphides. In the temperature range of 700–800 K, in austenitic steels, the atomic separation of the solid solution occurs, the intensity of which decreases upon alloying with titanium or phosphorus at concentrations of 1.0 and 0.1 wt %, respectively. At higher temperatures (about 950 K), the formed precipitates of the Ni₃Ti (γ') phase increase in size to 7–10 nm.

The martensite structure of the Ni₄₇Mn₄₂In₁₁ alloy has been studied, and crystallographic peculiarities of the structure realized after ten cyclic forward and reverse phase transformations have been shown. Each cycle includes the heating to a temperature corresponding to the existence of austenite and subsequent cooling to cryogenic temperatures. It was found that (107)-twinned martensite crystals can contact not only on the (10\(\bar 7\) ) plane, which, being the symmetry axis for the crystals, is not among the close-packed planes, but also on the (12\(\bar 7\) ) plane, which is among close packed planes but is not the symmetry axis.

Modern metastable steels with TRIP/TWIP effects have a unique set of physical-mechanical properties. They combine both high-strength and high-plasticity characteristics, which is governed by processes activated during deformation, namely, twinning, the formation of stacking faults, and martensitic transformations. To study the behavior of these phenomena in CrMnNi TRIP/TWIP steels and stainless CrNiMo steel, which does not have these effects in the temperature range under study, we used the method of acoustic emission and modern methods of signal processing, including the cluster analysis of spectral-density functions. The results of this study have been compared with a detailed microstructural analysis performed with a scanning electron microscope using electron backscatter diffraction (EBSD).

The effect of the preliminary high strain-rate deformation, performed via the method of dynamic channel-angular pressing (DCAP), and subsequent annealings on the tribological properties of a dispersionhardened Cu–0.092 wt % Cr–0.086 wt % Zr alloy has been investigated. It has been shown that the surfacelayer material of the alloy with a submicrocrystalline (SMC) structure obtained by the DCAP method can be strengthened using severe plastic deformation by sliding friction at the expense of creating a nanocrystalline structure with crystallites of 15–60 nm in size. It has been shown that the SMC structure obtained by the high strain-rate DCAP deformation decreases the wear rate of the samples upon sliding friction by a factor of 1.4 compared to the initial coarse-grained state. The maximum values of the microhardness and minimum values of the coefficient of friction and shear strength have been obtained in the samples preliminarily subjected to DCAP and aging at 400°С. The attained level of microhardness is 3350 MPa, which exceeds the microhardness of the alloy in the initial coarse-grained state by five times.