Chemical Composition of Sediments and Its Changes in the Center of the Modern Hydrothermal System in the Middle Valley of the Oceanic Ridge Juan de Fuca, Hole 858B ODP

The article presents the results of a study of changes in the chemical composition of Pleistocene sediments from Hole 858B, 38.6 m deep with a temperature gradient of 10‒11°C/m, drilled in the Middle Valley of the Juan de Fuca oceanic ridge (Northeast Pacific) in the “Dead Dog” hydrothermal field, in 20 m from “black smoker” with a temperature of 276°C. The content of petrogenic elements in these sediments was studied by XRD. For the first time, data on a large set of trace elements were obtained for this object using the ICP MS method. The change in the chemical composition of sediments occurred in the process of solution-rock interaction under conditions of a rapid increase in temperature downwards the section. In the Unit I, in its upper part (1.97‒10.41 m), the sediments are slightly altered at a temperature of about 17°C. In the lower part of the Unit I (12.70‒25.31 m) under conditions of average temperature (112‒197°C), the change in the content of petrogenic elements and trace elements is well pronounced. The chemical composition of the sediments of the Unit IIB and the Unit IID (25.31‒38.6 m) is most strongly changed in the temperature range from 112‒197°С to 320‒330°С. Changes in the content for most macroelements and trace elements in the sediments of Unit IIB and Unit IID are similar, with the difference that the decrease in the content of chemical elements is more pronounced in the sediments of the Unit IID. In them, the content of Cu, Zn, Ga, Rb, Sr, Ag, Cd, Sb, Cs, Ba, Tl, Bi, except for U, is significantly lower than in background sediments. The sediments of the the IID, as well as the sediments of the Unit IIB, contain less Ca, Na, K, P and more Mg. A lower content of chemical in these sediments can be considered as their removal from sediments under the process of solution-sediments interaction and enrichment of the solution with them, and their higher content, as its introduction into sediments from solution and, accordingly, depletion of these chemical elements in the solution. The results of studying the chemical composition of metalliferous sediments (Unit III, 0‒1.97 m) and sulfide layer IV (10.41‒12.70 m), as well as the chemical composition of unaltered background sediments from Holes 855A, C, D are presented.