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Vol 53, No 2 (2018)

Article

Determination of Minor Contents of Smectite Layers in the Dispersed Dioctahedral K-bearing Micaceous Minerals of the Illite, Aluminoceladonite, and Glauconite Composition

Sakharov B.A., Drits V.A.

Abstract

A theoretically substantiated technique has been elaborated for the precise determination of minor contents of smectite layers in the dioctahedral mixed-layer structures with a disordered alternation of K-bearing micaceous and ethylene glycol-saturated smectite layers. It is shown that observed positions of the possible mixed-layer mica–smectite structures in the d(003)obsd(007)obs or 2θ(003)obs–2θ(007)obs diagrams are distributed along a set of parallel straight lines. Data points of each straight line correspond to the mixed-layer structures with one and the same content of smectite layers. A complete matching of theoretical model was recorded in the positions of d(003)obsd(007)obs and 2θ(003)obs–2θ(007)obs pairs of the basal reflections determined in diffractograms simulated for 160 two-component mixed-layer mica–smectite structures differing in the thickness of alternating layers and their relative content. We studied samples of the dioctahedral K-bearing micas of the glauconite, illite, and aluminoceladonite composition with different thickness of micaceous layers. Positions of the mixed-layer structures of the studied samples on the 2θ(003)obs–2θ(007)obs and d(003)obsd(007)obs plots make it possible to visually determine the content of smectite layers in each structure accurate to 0.5%. The content of smectite layers in the studied samples varied from 2 to 15%. We obtained equations relating the thickness of smectite and micaceous layers for a specified content of smectite layers. They make it possible to determine the thickness correlation between specified mica and smectite layers. Analogous equations can be used to calculate the Wsm value in each sample for specified experimental values of d(001)mc and d(001)sm and d(003)obs or d(007)obs. The Wsm values coincide within an error limit of 0.2% with those based on the visual estimates in plots.

Lithology and Mineral Resources. 2018;53(2):91-109
pages 91-109 views

Mineralogical–Geochemical Features of Ice-Rafted Sediments in Some Arctic Regions

Maslov A.V., Shevchenko V.P., Bobrov V.A., Belogub E.V., Ershova V.B., Vereshchagin O.S., Khvorov P.V.

Abstract

The quantitative mineral composition estimated using the Rietveld method and some geochemical features are considered for bulk samples of the ice-rafted sediments (IRS) from some Arctic regions. Layer silicates in the studied samples vary from ~20 to ~50%. They are dominated by micas and their decomposition products (illite and likely some part of smectites) at significant contents of kaolinite, chlorite, and transformation/decomposition products of the latter. A significant content of illite and muscovite among layer silicates in most IRS samples suggests that sources of the sedimentary material were mainly mineralogically similar to modern bottom sediments of the East Siberian and Chukchi seas, as well as presumably sediments of the eastern Laptev Sea. It is suggested that a significant kaolinite fraction in IRS samples from the North Pole area can be caused by the influx of ice-rafted fine-grained sedimentary material from the Beaufort or Chukchi seas, where kaolinite is supplied from the Bering Sea. Positions of IRS data points in the (La/Yb)N–Eu/Eu*, (La/Yb)N–(Eu/Sm)N, and (La/Yb)N–Th diagrams show that the studied samples contain variable proportions of erosion products of both mafic and felsic magmatic rocks and/or sufficiently mature sedimentary rocks. This conclusion is confirmed by localization of IRS data points in the Th/Co–La, Si/Al–Ce, and Si/Al–Sr diagrams.

Lithology and Mineral Resources. 2018;53(2):110-129
pages 110-129 views

Sedimentation Model of Rocks of the Pokur Formation: Basis for the Prediction of Filtration-Volumetric Characteristics (Upper Cretaceous, West Siberia)

Zhemchugova V.A., Berbenev M.O.

Abstract

The HC-rich Upper Cretaceous rocks in the West Siberian petroliferous basin comprise genetically heterogeneous sediments, resulting in the specificity of morphology, structure, and properties of natural reservoirs therein. One of the possible techniques for more reliable predictions of reservoir rock characteristics is the utilization of results of sedimentation modeling based on the complex interpretation of borehole and seismic data. The paper presents an example of the realization of such approach for refining the structure of oil-and-gas pools in the Pokur Formation of the Russko-Chasel megaswell.

Lithology and Mineral Resources. 2018;53(2):130-139
pages 130-139 views

Geochemical Features and Geodynamic Settings of the Formation of Cretaceous Terrigenous Rocks of the West Sakhalin Terrane

Malinovsky A.I.

Abstract

The geochemical composition of Cretaceous terrigenous rocks of the West Sakhalin terrane is analyzed and their paleogeodynamic interpretation is suggested. It is revealed that the rocks are characterized by the low maturity of clastic material. They contain fragments of both volcanomictic and sialic material and in composition correspond to graywackes, being petrogenic or “first cycle” rocks. The geochemical data were generalized and interpreted on the basis of their comparison with compositions of the present-day and ancient rocks formed in known geodynamic settings. The obtained results indicate that terrigenous rocks of the terrane were formed in a pull-apart basin at an active continental margin. The source area, which supplied clastic material in this sedimentation basin during the Berriasian–Danian, included a sialic land made up of granite-metamorphic and sedimentary rocks and the mature (deeply dissected) ensialic Moneron–Samarga island arc, which was accreted to the continental margin at the moment of basin initiation. Sediments were accumulated in general along the continent–ocean boundary against the background of large-scale sinistral transform strike-slip movements of the Izanagi Plate relative to the Eurasian continent.

Lithology and Mineral Resources. 2018;53(2):140-158
pages 140-158 views

Biogenic Microstructures in Stromatolites of the Baikal–Patom Highland: Results of Complex Study

Litvinova T.V., Sergeev V.N.

Abstract

Precambrian stromatolites were studied with a complex approach including two complementary methods. The biogenic origin of ultramicrostructures examined with SEM was supported by the traditional optical microscopy. The paper addresses columnar-stratiform stromatolites of the Vendian Chencha Formation in the Ura Uplift (Baikal–Patom Highland, Central Siberia) and fossilized remains of coccoidal and filamentous microorganisms therein: cyanobacteria Eoentophysalis, hormogonian cyanobacteria Siphonophycus and, probably, Eomicrocoleus. The unraveled community of stromatolite builders includes the major organisms commonly observed in the Precambrian microbiota. Stromatolites of the Chencha Formation contained not only cyanobacteria, but also remains of eukaryotic microorganisms, including likely testate amoebae and acanthomorphic acritarchs. It is shown that the complex approach rules out incorrect determination of biota and significantly enhances concepts of the origin and formation of stromatolites, as well as the participation of microorganisms in their formation.

Lithology and Mineral Resources. 2018;53(2):159-169
pages 159-169 views

Rhythmic Structure of the Productive Sylvinite Lode in the Gremyachinsk Deposit (Southern Volga Monocline)

Moskovskii G.A., Goncharenko O.P., Solomon M.V.

Abstract

The rhythmic structure of productive sylvinite lode in the Gremyachinsk potash deposit is considered. Data are obtained on the composition of the potash horizon in two holes drilled on the northern and southern flanks of the deposit. Two types of rhythmicity are established in the sylvinites: one type is formed by halogenic processes; the other, by the influx of terrigenous material. It is revealed that the sylvinite horizon in the northern and southern parts of the deposit differs in the mineral composition and conditions of formation.

Lithology and Mineral Resources. 2018;53(2):170-177
pages 170-177 views

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