Vol 52, No 5 (2017)

Geochemical studies of pyrite crystals from the mud volcanic ejecta in Azerbaijan were studied. It is shown that all of them have cubic shape. Determination of the sulfur isotope composition revealed a wide variation range of δ³⁴S values from–27.0 to +26.4‰. Signs of spatial zonation were recorded in the distribution of δ³⁴S values—lower values are confined to the present-day coastline of the Caspian Sea. Appearance of pyrite with a high share of ³⁴S is attributed to sulfate reduction that takes place in an environment with excess organic matter. It is supposed that the isotopically heavy sulfides represent the “neck” facies that are formed at the periphery of mud volcanic conduits at the contact of the hydrocarbon-rich mud volcanic fluids with stratal waters of host sediments.

In the Kaliningrad region, sediments of the Upper Eocene Prussian Formation accommodates the world’s largest explored amber deposits (up to 90% of world reserves). They are also partly tracked on the shelf of the southeastern Baltic region and subjected to bottom erosion, which is particularly intense during storm activity in the sea. Recent alongshore currents transport amber fragments over great distances, resulting in the formation of new (secondary) amber-bearing deposits in Holocene sediments in some places. The paper addresses formation conditions of such deposits. Catastrophic events, such as hydrospheric floods provoked by the regional glaciation, meteorite falls, and earthquakes (tsunamis), are of great significance.

The paper reports the results of study of the main placer-forming minerals (ilmenite and zircon) from the Umyt’ya coastal–marine placer in the western part of the Khanty-Mansi Autonomous District, Yugra. Microprobe study of 1450 zircon grains taken from the upper and lower ore bodies of the Umyt’ya placer (29 samples) and their comparison with zircon in magmatic rocks from the adjacent folded framing of the North and Nether-Polar Urals (40 analyses) allowed us to recognize five geochemical types of the mineral: Aurbakh (prevailing in the Umyt’ya placer), Severorudnichnyi, Tagil-Kytlym, Shemur, and unknown source. Crystallomorphological characteristics of the identified geochemical types of zircon are given. According to the microprobe data (300 analyses), ilmenite is subdivided into six groups. Comparison of these groups with the composition of ilmenite from magmatic complexes of the North and Nether-Polar Urals showed that they correspond to the same complexes as zircon. Based on peculiarities of the geological structure of the eastern slope of the North and Nether-Polar Urals, four separate areas were identified, each comprising spatially close magmatic complexes regarded as possible sources for ore minerals of the placers: Shchekur’ya–Khorasyur, Yalpigner–Chistop, Vizhai–Ivdel, and Denezhkin Kamen. Based on additional criteria, the Yalpigner–Chistop area was the main source for the Umyt’ya placer.