Open Access Open Access  Restricted Access Access granted  Restricted Access Subscription Access

Vol 51, No 1 (2016)

Article

Buried ferromanganese nodules of the Magellan Seamounts

Mel’nikov M.E., Avdonin V.V., Pletnev S.P., Sedysheva T.E.

Abstract

Buried ferromanganese nodules and their stratiform accumulations (nodule horizons), which are widespread in sedimentary sequences of the Magellan Seamounts, have been studied in core obtained by shallow drilling on its guyots in the course of expeditions of the R/V Gelendzhik in 2001–2010. The study included description of morphological features, structure, and composition of buried nodules, the assessment of their geological age, and the analysis of host geological environments. It was revealed that nodule horizons are developed in areas with unstable hydroand lithodynamic conditions. The frequent changes of these conditions were responsible for the formation of such nodule horizons and overlying ferromanganese crusts. It is shown that the crusts and nodules developed at the surface of bottom sediments and nodules buried within them are characterized by the similar structure and composition, which indicates their belonging to the same ore formation, i.e., ferromanganese ores of seamounts. The age of buried nodule horizons is correlated with that of layers in ferromanganese crusts, on the one hand, and with the age of host sedimentary complexes defined in the Magellan Seamounts area. The buried nodules include both Cenozoic and Late Cretaceous varieties. The finds of Cenomanian nodule horizons provide grounds for the assumption that the formation of ferromanganese ores on gyuots of the Magellan Seamounts could start prior to the Senonian.

Lithology and Mineral Resources. 2016;51(1):1-12
pages 1-12 views

Absorbed complex of riverine solid substances and its role in geochemical balance of the ocean

Savenko A.V., Savenko V.S.

Abstract

Data on the composition of the absorbed complex of riverine solid substances and its transformation in marine environments obtained from field observations and experimental investigations are systematized and generalized. Average values of the specific surface of the riverine suspended particulates (~20 m2/g) and the total exchange capacity of solid substances of the continental runoff (~28 mg-equiv/100 g or 280 g-equiv/t of the transported terrigenous material) are determined. It is shown that the composition of the absorbed complex in the riverine suspended particulates, as well as bottom sediments of rivers and inland water bodies differs principally from that of bottom sediments in oceans and seas: Ca dominates in the first case; Na, in the second case. When the riverine terrigenous material enters oceans and seas, the composition of the absorbed complex is subjected to the ion-exchange transformation reflected in the replacement of exchange Ca (~80%) mainly by Na and also by K and Mg of seawater. This process is responsible for the influx of 45.5 Mt/yr of dissolved Ca to ocean and the removal of 37.3, 12.8, and 3.9 Mt/yr of Na, K, and Mg, respectively. The relative transport of Ca, Na, K, and Mg to ocean with the river runoff is +7.5,–12.3,–22.4, and–2.6%, respectively.

Lithology and Mineral Resources. 2016;51(1):13-37
pages 13-37 views

Black shales and other sediments with high organic matter contents in Phanerozoic climatic cycles: Communication 2. Black shales during the Pangea existence

Konyukhov A.I.

Abstract

According to recent concepts, the Earth surface was permanently transformed during its geological history. Some stages of its evolution were marked by the convergence of separate continental blocks to result in the formation of supercontinents, which resisted successfully centrifugal processes. Other stages were characterized by the opposite tendency: after their long existence, the supercontinents became disintegrated into several large and small blacks, the motion of which was accompanied by opening of new sea basins and closure of former basins with the oceanic crust. The second half of the Paleozoic was marked by amalgamation of large continental blocks. In the Devonian, collision between Laurentia and Baltica culminated in the formation of the Euroamerica continent. After the closure of the Ural paleocean in the terminal Carboniferous–initial Permian, it was united with the Siberian and Kazakhstan continental blocks. These events provided the prerequisites for the formation of a new supercontinent (Pangea), which acquired its final configuration at the end of the Permian. One of its segments located mainly south of the equator included Gondwana. Another segment located northward included Euroamerica, Kazakhstan, Siberian, and two China continental blocks. During its geological history, Pangea suffered many dramatic events including several extinctions of organisms. The most significant event took place in the terminal Permian–initial Triassic and at the transition between the Triassic and Jurassic periods.

Lithology and Mineral Resources. 2016;51(1):38-60
pages 38-60 views

Distribution of helium and hydrogen in sediments and water on the Sakhalin slope

Shakirov R.B., Syrbu N.S., Obzhirov A.I.

Abstract

During the geological survey and prospecting, helium and hydrogen are recognized indicators of minerals, deep-seated faults, seismic activity, and ascending deep fluids. Their anomalous concentrations also serve as a marker of metamorphic processes. Helium survey is applied for tracing deep-seated faults and mapping permeable zones. In this work, the first results of gas geochemical survey in marine sediments and water to study the distribution of helium and hydrogen and their relation with the seismic activity of some geological structures in the southwestern Sea of Okhotsk and northern Sea of Japan. Anomalies of these gases (He up to 60 ppm, H up to 120 ppm) were identified in the hydrate-bearing sediments in the fault zones. It was also found that helium concentrations in the water column of the Tatar Strait are higher than in the studied area of the Sea of Okhotsk, possibly, due to the difference in geological structure and seismotectonic activation. Moreover, coal layers could be a significant source of methane in the gashydrate-bearing layers of the Tatar Strait.

Lithology and Mineral Resources. 2016;51(1):61-73
pages 61-73 views

Uranium, thorium, and potassium in black shales of the Bazhenov Formation of the West Siberian marine basin

Zanin Y.N., Zamirailova A.G., Eder V.G.

Abstract

Contents and distribution of U, Th, and K in rocks of the so-called normal and anomalous sections of the Upper Jurassic–Lower Cretaceous Bazhenov Formation in the West Siberian marine basin are examined. In normal sections of this unit, the most widespread clayey–siliceous rocks deposited in the course of slow “background” sedimentation, are characterized by high (relative to black shales) contents of U (66.5 ppm) but moderate contents of Th (5.07 ppm) and K (0.81%). In mudstones identified as turbidite sediments with high sedimentation rate, contents of these elements are 11.68 ppm, 11.00 ppm, and 2.70%, respectively. In rare clayey–silty sediments of anomalous sections marked by maximal deposition rates, contents of these elements are 2.15 ppm, 3.78 ppm, and 2.15%, respectively. Uranium is associated mainly with organic matter and partly with apatite (phosphate clasts of fish skeletons) and calcite; thorium, with clay minerals; potassium, with clay minerals and K-feldspar. The U content is 345 ppm at high apatite concentration (7%).

Lithology and Mineral Resources. 2016;51(1):74-85
pages 74-85 views

Desalting of sodium and potassium chlorides at the final stages of halogenesis: Evidence from the Gremyachinsk potash deposit in the Caspian basin

Moskovskii G.A., Goncharenko O.P., Ilin K.K.

Abstract

The study of “productive” intervals of the Gremyachinsk potash deposit showed that the precipitation of potassic and potassic–magnesium salts was accompanied by large-scale desalting of sodium chloride owing to the interaction of concentrated solutions from the given part of the saliferous basin with diluted solutions. The constant influx of diluted brine was characterized by the high content of sodium chloride, which led to the large-scale precipitation of halite as lenses, crusts, and accumulations of random morphology. Based on the ultramicrochemical analysis of the composition of brine inclusions in halites of different stages of densification, it is suggested that this process was accompanied by the growth of K ion concentrations in the brine and the subsequent desalting of potassium chloride in the carnallite stage brine with the formation of rocks of the carnallite–sylvinite paragenesis.

Lithology and Mineral Resources. 2016;51(1):86-91
pages 86-91 views