On the mechanism of growth of lactose crystals from supersaturated solutions
- Authors: Fialkova E.А.1, Shevchuk V.B.1, Gnezdilova A.I.1, Vinogradova Y.V.1, Baronov V.I.1
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Affiliations:
- Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
- Issue: Vol 69, No 4 (2024)
- Pages: 720-729
- Section: CRYSTAL GROWTH
- URL: https://journals.rcsi.science/0023-4761/article/view/264438
- DOI: https://doi.org/10.31857/S0023476124040191
- EDN: https://elibrary.ru/XBLCGF
- ID: 264438
Cite item
Abstract
The substantiation of the existence of cavitation zones on the edges of a growing lactose crystal and its driving role in the crystal growth process is presented. It is shown that the most favorable conditions for the conversion of dissolved lactose into its crystalline form are created around the edges of the crystal in the phase transition zones. The size of the phase transition zone of the crystallizing substance is calculated and compared with the available data on the size of crystalline nuclei. The values of the radius of cavitation zones were obtained, which amounted to: nanometers (for a crystal with a size of 60.5 microns, at a temperature of 30°C and supersaturation of 0.55) and nanometers (for a crystal with a size of 84 microns, at a temperature of 50°C and supersaturation of 1.88). A mathematical model of the growth rate of lactose crystals in a supersaturated solution is proposed. The possibility of studying the mechanisms of crystallization and determining the growth rate of lactose crystals is substantiated, based on the theory of dynamic interaction of bodies and liquids by A. Y. Milovich.
About the authors
E. А. Fialkova
Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
Email: vshevchuk@list.ru
Russian Federation, Vologda
V. B. Shevchuk
Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
Author for correspondence.
Email: vshevchuk@list.ru
Russian Federation, Vologda
A. I. Gnezdilova
Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
Email: vshevchuk@list.ru
Russian Federation, Vologda
Y. V. Vinogradova
Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
Email: vshevchuk@list.ru
Russian Federation, Vologda
V. I. Baronov
Federal State Budgetary Educational Institution of Higher Education “Vologda State Dairy Farming Academy by N. V. Vereshchagin”
Email: vshevchuk@list.ru
Russian Federation, Vologda
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