Structure, Microstructure, and Properties of Modified Ceramics (Na,Sr)0.5Bi0.5TiO3
- Авторлар: Kaleva G.1, Politova E.1, Mosunov A.2, Stefanovich S.2, Ilina T.3, Kiselev D.3, Sadovskaya N.4
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Мекемелер:
- Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia
- Moscow State University, 119991, Moscow, Russia
- National University of Science and Technology MISiS, 119049, Moscow, Russia
- Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia
- Шығарылым: Том 68, № 5 (2023)
- Беттер: 817-825
- Бөлім: НАНОМАТЕРИАЛЫ, КЕРАМИКА
- URL: https://journals.rcsi.science/0023-4761/article/view/137438
- DOI: https://doi.org/10.31857/S002347612360043X
- EDN: https://elibrary.ru/EDKICO
- ID: 137438
Дәйексөз келтіру
Аннотация
Single-phase ceramic samples of new compositions (Na1 – хSrх)0.5Bi0.5TiO3 (x = 0–0.5), including those modified by additives of SiO2 and ZnO oxides, have been obtained by solid-phase synthesis. The crystal structure and microstructure of these samples, as well as their dielectric, nonlinear optical, and local piezoelectric properties, have been studied. The formation of a perovskite-type phase with a pseudocubic unit cell in all synthesized samples and an increase in the cell volume as a result of partial substitution of perovskite structure cations are established. A decrease in the temperature of ferroelectric phase transitions (confirmed by the methods of dielectric spectroscopy and laser second-harmonic generation) to the tetragonal paraelectric phase is revealed. Remanent piezoelectric hysteresis loops are obtained for the synthesized samples in the polarization switching mode; this result confirms the occurrence of ferroelectric polarization switching.
Авторлар туралы
G. Kaleva
Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
E. Politova
Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
A. Mosunov
Moscow State University, 119991, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
S. Stefanovich
Moscow State University, 119991, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
T. Ilina
National University of Science and Technology MISiS, 119049, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
D. Kiselev
National University of Science and Technology MISiS, 119049, Moscow, Russia
Email: kaleva@nifhi.ru
Россия, Москва
N. Sadovskaya
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia
Хат алмасуға жауапты Автор.
Email: kaleva@nifhi.ru
Россия, Москва
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