Structure, Microstructure, and Properties of Modified Ceramics (Na,Sr)0.5Bi0.5TiO3

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Single-phase ceramic samples of new compositions (Na1 – хSrх)0.5Bi0.5TiO3 (x = 0–0.5), including those modified by additives of SiO2 and ZnO oxides, have been obtained by solid-phase synthesis. The crystal structure and microstructure of these samples, as well as their dielectric, nonlinear optical, and local piezoelectric properties, have been studied. The formation of a perovskite-type phase with a pseudocubic unit cell in all synthesized samples and an increase in the cell volume as a result of partial substitution of perovskite structure cations are established. A decrease in the temperature of ferroelectric phase transitions (confirmed by the methods of dielectric spectroscopy and laser second-harmonic generation) to the tetragonal paraelectric phase is revealed. Remanent piezoelectric hysteresis loops are obtained for the synthesized samples in the polarization switching mode; this result confirms the occurrence of ferroelectric polarization switching.

Авторлар туралы

G. Kaleva

Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

E. Politova

Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

A. Mosunov

Moscow State University, 119991, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

S. Stefanovich

Moscow State University, 119991, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

T. Ilina

National University of Science and Technology MISiS, 119049, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

D. Kiselev

National University of Science and Technology MISiS, 119049, Moscow, Russia

Email: kaleva@nifhi.ru
Россия, Москва

N. Sadovskaya

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

Хат алмасуға жауапты Автор.
Email: kaleva@nifhi.ru
Россия, Москва

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Қосымша файлдар


© Г.М. Калева, Е.Д. Политова, А.В. Мосунов, С.Ю. Стефанович, Т.С. Ильина, Д.А. Киселев, Н.В. Садовская, 2023

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