The Role of Chemical Pressure in the Formation of the Structure and Barocaloric Properties of Complex Fluorides and Oxyfluorides
- Авторлар: Flerov I.1,2, Gorev M.1,2, Bogdanov E.1,3, Laptash N.4
-
Мекемелер:
- Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
- Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russia
- Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, Russia
- Institute of Chemistry, Far Eastern Branch, Vladivostok, Russia
- Шығарылым: Том 68, № 5 (2023)
- Беттер: 776-789
- Бөлім: ФИЗИЧЕСКИЕ СВОЙСТВА КРИСТАЛЛОВ
- URL: https://journals.rcsi.science/0023-4761/article/view/137424
- DOI: https://doi.org/10.31857/S0023476123600477
- EDN: https://elibrary.ru/DJYWHW
- ID: 137424
Дәйексөз келтіру
Аннотация
The role of chemical pressure as an effective tool in the processes of formation of initial and distorted (as a result of structural transformations) phases, thermodynamic properties, and direct and inverse barocaloric effects in some complex oxyfluorides and fluorides with octahedral, tetrahedral, and spherical anion and cation groups in the structure has been studied. It is found that, due to the small temperature hysteresis and high baric sensitivity of materials, the maximum values of absolute and integral barocaloric characteristics can be implemented at low pressures. Correspondingly, the temperature range of reversibility of thermodynamic cycles based on fluorides/oxyfluorides as solid-state coolants can be expanded.
Авторлар туралы
I. Flerov
Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia; Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russia
Email: flerov@iph.krasn.ru
Россия,
Красноярск; Россия, Красноярск
M. Gorev
Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia; Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russia
Email: flerov@iph.krasn.ru
Россия,
Красноярск; Россия, Красноярск
E. Bogdanov
Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia; Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, Russia
Email: flerov@iph.krasn.ru
Россия,
Красноярск; Россия,
Красноярск
N. Laptash
Institute of Chemistry, Far Eastern Branch, Vladivostok, Russia
Хат алмасуға жауапты Автор.
Email: flerov@iph.krasn.ru
Россия, Владивосток
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