GROWTH OF KR3F10 (R = Tb–Er) COMPOUNDS BY THE VERTICAL DIRECTIONAL CRYSTALLIZATION METHOD. III: MELTING CHARACTER AND NONSTOICHIOMETRY OF CUBIC KHo3F10AND KEr3F10 SINGLE CRYSTALS
- 作者: Karimov D.1, Buchinskaya I.1, Grebenev V.1
-
隶属关系:
- Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia
- 期: 卷 68, 编号 1 (2023)
- 页面: 131-137
- 栏目: CRYSTAL GROWTH
- URL: https://journals.rcsi.science/0023-4761/article/view/137384
- DOI: https://doi.org/10.31857/S0023476123010125
- EDN: https://elibrary.ru/DOXRLQ
- ID: 137384
如何引用文章
详细
KR3F10 (R = Ho, Er; sp. gr. ) crystals have been grown by the vertical directional crystallization. The incongruent melting of these compounds is experimentally established, and the temperatures of the corresponding thermal effects are determined. Narrow regions of homogeneity are found for the studied crystals; these regions are also characteristic of the entire series of KR3F10 crystals under study. The cubic lattice parameter monotonically decreases along the crystal length and varies in the range of 11.5782(2)–11.5654(5) Å for KHo3F10 and 11.5225(1)–11.5102(4) Å for KEr3F10. The conditions for growing KR3F10 crystals of optical quality from melt are optimized.
作者简介
D. Karimov
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia
Email: dnkarimov@gmail.com
Россия, Москва
I. Buchinskaya
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia
Email: buchinskayaii@gmail.com
Россия, Москва
V. Grebenev
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences, Moscow, 119333 Russia
编辑信件的主要联系方式.
Email: buchinskayaii@gmail.com
Россия, Москва
参考
- Хайдуков Н.М., Филатова Т.Г., Икрами М.Б., Федоров П.П. // Неорган. материалы. 1993. Т. 29. № 7. С. 992.
- Vedrine A., Boutonnet R., Sabatier R., Cousseins J.C. // Bull. Soc. Chim. Fr. Pt. 1. 1975. № 3–4. P. 445.
- Винокуров А.В., Малкин Б.З., Столов А.Л. // ФТТ. 1996. Т. 38. № 3. С. 751.
- Chamberlain S.L., Corruccini L.R. // J. Phys. Chem. Solids. 2006. V. 67. № 4. P. 710. https://doi.org/10.1016/j.jpcs.2005.08.091
- Vasyliev V., Villora E.G., Nakamura M. et al. // Opt. Express. 2012. V. 20. № 12. P. 14460. https://doi.org/10.1364/OE.20.014460
- Yakovlev A., Balabanov S., Permin D. et al. // Opt. Mater. 2020. V. 101. P. 109750. https://doi.org/10.1016/j.optmat.2020.109750
- Karimov D., Buchinskaya I., Sorokin N. // Z. Krist. – Cryst. Mater. 2022. V. 237. № 10–12. P. 429. https://doi.org/10.1515/zkri-2022-0032
- Fangtian Y., Shihua H., Qiufeng S. // J. Rare Earths. 2010. V. 28. № 5. P. 676. https://doi.org/10.1016/S1002-0721(09)60177-0
- Cao C., Guo S., Moon B.K. et al. // Mater. Chem. Phys. 2013. V. 139. № 2–3. P. 609. https://doi.org/10.1016/j.matchemphys.2013.02.005
- Li Ch., Xu Z., Yang D. et al. // Cryst. Eng. Commun. 2012. V. 14. № 2. P. 670. https://doi.org/10.1039/c1ce06087b
- Müller-Bunz H., Schleid T. // Z. Anorg. Allg. Chem. 2007. B. 633. № 15. S. 2619. https://doi.org/10.1002/zaac.200700329
- Karimov D., Buchinskaya I., Arkharova N. et al. // Crystals. 2021. V. 11. № 3. P. 285. https://doi.org/10.3390/cryst11030285
- Шаймурадов И.Б., Решетникова Л.П., Новоселова А.В. // Изв. АH СССР. Неорган. материалы. 1974. Т. 10. № 8. С. 1468.
- Федоров П.П. // Журн. неорган. химии. 1999. Т. 44. № 11. С. 1791.
- Решетникова Л.П., Шаймурадов И.Б., Новоселова А.В. // Изв. АH СССР. Неорган. материалы. 1979. Т. 15. № 7. С. 1232.
- Aleonard S., Labeau M., Le Fur Y., Gorius M.F. // Mater. Res. Bull. 1973. V. 8. № 6. P. 605. https://doi.org/10.1016/0025-5408(73)90053-6
- Labeau M., Le Fur Y., Aleonard S. // J. Solid State Chem. 1974. V. 10. № 3. P. 282. https://doi.org/10.1016/0022-4596(74)90036-x
- Grzechnik A., Khaidukov N., Friese K. // Dalton Trans. 2013. V. 42. № 2. P. 441. https://doi.org/10.1039/C2DT31483E
- Wani B.N., Rao U.R.K. // J. Solid State Chem. 1994. V. 112. № 1. P. 199. https://doi.org/10.1006/jssc.1994.1288
- Каримов Д.Н., Комарькова О.Н., Сорокин Н.И. и др. // Кристаллография. 2010. Т. 55. № 3. С. 556.