ОСОБЕННОСТИ ДВОЙНОГО ЭЛЕКТРИЧЕСКОГО СЛОЯ ВОКРУГ СФЕРИЧЕСКИХ ЧАСТИЦ. МОДЕЛЬ ПУАССОНА–ГЕЛЬМГОЛЬЦА–БОЛЬЦМАННА

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Аннотация

Модель Пуассона–Гельмгольца–Больцмана использована для исследования свойств двойного электрического слоя, формирующегося вблизи одиночной слабозаряженной сферической частицы, окруженной раствором 1:1 электролита. Разделяя на кулоновские и некулоновские (задаваемые потенциалом Юкавы) взаимодействия между ионами в растворе, а также между ионами и частицей, получены математические выражения для профилей соответствующих потенциалов вблизи частицы в функции основных параметров модели. При варьировании значений ключевых параметров найдены как монотонные, так и немонотонные профили электростатического потенциала, наблюдается смена знака потенциала, вследствие чего возникают явления инверсии и обращения заряда. Определены условия, при которых наступают инверсия и обращение знака потенциала частицы. Рассмотрена зависимость потенциала нулевого заряда от размера частиц, концентрации раствора одновалентного электролита и поверхностной плотности источника некулоновских сил.

Об авторах

А. И. Долинный

Институт физической химии и электрохимии им. А.Н. Фрумкина РАН

Email: dolinyi@mail.ru
Москва, Россия

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