Noncovalent Stabilization of Water-Soluble Zinc Phthalocyaninate in Graphene Oxide Hydrosol

A. G. Nugmanova; Нугманова А. Г.; A. I. Gorshkova; Горшкова А. И.; A. V. Yagodin; Ягодин А. В.; A. A. Averin; Аверин А. А.; M. A. Kalinina; Калинина М. А.

doi:10.31857/S0023291223600700

Noncovalent Stabilization of Water-Soluble Zinc Phthalocyaninate in Graphene Oxide Hydrosol

Authors: Nugmanova A.G.¹, Gorshkova A.I.², Yagodin A.V.¹, Averin A.A.¹, Kalinina M.A.¹
Affiliations:
1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia
2. Department of Materials Sciences, Moscow State University, 119991, Moscow, Russia
Issue: Vol 85, No 6 (2023)
Pages: 781-794
Section: Articles
URL: https://journals.rcsi.science/0023-2912/article/view/231814
DOI: https://doi.org/10.31857/S0023291223600700
EDN: https://elibrary.ru/XTLVXB
ID: 231814

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Abstract

The possibility of stabilization of zinc(II) 2,3,9,10,16,17,23,24-octa[(3,5-sodium biscarboxylate)phenoxy] phthalocyaninate (ZnPc16) by its hybridization with the surface of graphene oxide (GO) sheets via van der Waals or coordination bonds with functional groups of the carbon matrix in the GO hydrosols has been investigated. A combination of physicochemical analysis methods (scanning electron microscopy, fluorescence microscopy, powder X-ray diffraction, and Raman spectroscopy) has been employed to confirm the integration of ZnPc16 with GO nanosheets and to study the morphology and structure of the obtained hybrid materials. Using electronic absorption spectroscopy, it has been found that, regardless of the hybridization method, the binding of the macrocycles to the inorganic particles increases the stability of ZnPc16 in an aqueous medium being irradiated with visible light. The analysis of spectral kinetic data has shown that, in contrast to the system obtained by direct integration of ZnPc16 and GO, the hybrid material formed by coordination bonding of the components via zinc acetate (Zn(OAc)2) as a binding metal cluster is able to exhibit photocatalytic properties in oxidative photodegradation of some model organic pollutant substrates (rhodamine 6G, 1,5-dihydroxynaphthalene, and 1,4-nitrophenol). The proposed colloid-chemical approach to the stabilization of photoactive water-soluble phthalocyaninates makes it possible to increase their resistance to photoinduced self-oxidation and can be adapted for various derivatives of tetrapyrrole compounds possessing photosensitizing properties.

Keywords

hybrid materials, supramolecular self-assembly, heterogeneous photocatalysis, phthalocyanines, graphene oxide

References

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