WATER-SOLUBLE INTERPOLYELECTROLYTE COMPLEX BASED ON POLY(DIALLYLDIMETHYLAMMONIUM CHLORIDE) AND SODIUM POLYACRYLATE AS A COMPONENT FOR CREATING STABLE BIOCIDAL COATINGS

V. A. PIGAREVA; Пигарева В. А.; A. V. BOL’SHAKOVA; Большакова А. В.; V. I. MARINA; Марина В. И.; A. V.  SYBACHIN; Сыбачин А. В.

doi:10.31857/S0023291223600190

WATER-SOLUBLE INTERPOLYELECTROLYTE COMPLEX BASED ON POLY(DIALLYLDIMETHYLAMMONIUM CHLORIDE) AND SODIUM POLYACRYLATE AS A COMPONENT FOR CREATING STABLE BIOCIDAL COATINGS

Authors: PIGAREVA V.A.¹, BOL’SHAKOVA A.V.¹^,2, MARINA V.I.¹, SYBACHIN A.V.¹
Affiliations:
1. Department of Chemistry, Moscow State University, Moscow, Russia
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia
Issue: Vol 85, No 3 (2023)
Pages: 366-375
Section: Articles
Submitted: 16.10.2023
Published: 01.05.2023
URL: https://journals.rcsi.science/0023-2912/article/view/137243
DOI: https://doi.org/10.31857/S0023291223600190
EDN: https://elibrary.ru/ZPYSCB
ID: 137243

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Abstract

Polycation-based coatings represent a promising class of protective antimicrobial coatings. Water-soluble complexes of poly(diallyldimethylammonium chloride) (PDADMAC) with sodium polyacrylate (PANa) have been studied by turbidimetry. It has been shown that the addition of the polyanion (12 mol %) to the polycation leads to the formation of an interpolyelectrolyte complex (IPEC) stable with respect to phase separation in water-salt media with salt concentrations as high as 0.1–0.2 M. In contrast to the traditional method of obtaining coatings from IPEC by layer-by-layer deposition, we have studied the preparation of the coatings directly from a solution of water-soluble IPEC on a hydrophilic glass surface and a surface of more hydrophobic polycarbonate. It has been found that the formation of IPEC makes it possible to increase the resistance of the coating to wash-off with water compared to the individual PDADMAC coating on both types of substrates.

References

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