Отправить статью по E-mail Mesoporous Aluminosilicates in the Synthesis of N-Heterocyclic Compounds
- Авторы: Grigor’eva N.G.1,2, Agliullin M.R.1,2, Kostyleva S.A.1, Bubennov S.V.1, Bikbaeva V.R.2, Gataulin A.R.1, Filippova N.A.1, Kutepov B.I.1,2, Narender N.3
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Учреждения:
- Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
- Ufa State Petroleuml Technological University
- CSIR-Indian Institute of Chemical Technology Uppal Road, Telangana State
- Выпуск: Том 60, № 6 (2019)
- Страницы: 733-743
- Раздел: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/164303
- DOI: https://doi.org/10.1134/S0023158419020022
- ID: 164303
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Аннотация
The catalytic properties of samples of amorphous mesoporous aluminosilicate ASM with different Si/Al molar ratios (40, 80, 160) were studied in the synthesis of practically important pyridines (by the interaction of С2–С5 alcohols with formaldehyde and ammonia, cyclocondensation of acetaldehyde and propionic aldehyde with ammonia), dialkylquinolines and alkyltetrahydroquinolines (by reaction of aniline with C3, C4 aldehydes) and alkyldihydroquinolines (by interaction of aniline with ketones, acetone and acetophenone). It is found that mesoporous aluminosilicate ASM sample with a molar ratio of Si/Al = 40, which has the highest acidity among the studied samples, exhibits the highest activity and selectivity in these reactions.
Об авторах
N. Grigor’eva
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Автор, ответственный за переписку.
Email: ngg-ink@mail.ru
Россия, Ufa, 450075; Ufa, 450062
M. Agliullin
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Россия, Ufa, 450075; Ufa, 450062
S. Kostyleva
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Россия, Ufa, 450075
S. Bubennov
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Россия, Ufa, 450075
V. Bikbaeva
Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Россия, Ufa, 450062
A. Gataulin
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Россия, Ufa, 450075
N. Filippova
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Россия, Ufa, 450075
B. Kutepov
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Россия, Ufa, 450075; Ufa, 450062
Nama Narender
CSIR-Indian Institute of Chemical Technology Uppal Road, Telangana State
Email: ngg-ink@mail.ru
Индия, Tarnaka, Hyderabad, 500 007
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