A Change in the Specific Conductance of Solutions of High-Vanadium Heteropoly Acids in Redox Processes
- Autores: Rodikova Y.1, Zhizhina E.1
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Afiliações:
- Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
- Edição: Volume 60, Nº 6 (2019)
- Páginas: 790-795
- Seção: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/164308
- DOI: https://doi.org/10.1134/S0023158419050070
- ID: 164308
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Resumo
Changes in the values of specific conductance χ of the solutions of high-vanadium Mо−V−Р heteropoly acids (HPA-х) in redox processes are determined for the first time for the HPA-7 solution of the overall composition Н10Р3Мо18V7O84, which is a highly efficient catalyst for oxidation processes. The dependences of χ on [HPA-7] at different temperatures and degrees of reduction m and the dependence of χ on m, are found. The relationship between χ and the equilibrium composition of the HPA-7 solution is shown. It was confirmed that the regenerated HPA-7 solutions completely restore their conductance and other physicochemical properties (redox potential E, density, viscosity, and pH), thereby proving the high stability as homogeneous catalysts of oxidative processes.
Sobre autores
Yu. Rodikova
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Email: zhizh@catalysis.ru
Rússia, Novosibirsk, 630090
E. Zhizhina
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
Autor responsável pela correspondência
Email: zhizh@catalysis.ru
Rússia, Novosibirsk, 630090