CO oxidation with oxygen of the catalyst and gas-phase oxygen over (0.5−15)%СоО/СеО2


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The CO adsorption species on Co3O4 and (0.5-15%)CoO/CeO2 catalysts have been investigated by temperature-programmed desorption and IR spectroscopy. At 20°C, the largest amount of CO is adsorbed on the 5%CoO/CeO2 sample to form, on Com2+On2+ clusters, hydrogen-containing, bidentate, and monodentate carbonate complexes, whose decomposition is accompanied by CO2 desorption at 300 and 450°C (1.1 × 1020 g–1). The formation of the carbonates is accompanied by the formation of Co+ cations and Co0, on which carbonyls form. The latter decompose at 20, 90, and 170°C to release CO (2.7 × 1019 g–1). Part of the carbonyls oxidizes to CO2 upon oxygen adsorption, and the CO2 undergoes desorption at 20°C. Adsorbed oxygen decreases the decomposition temperature of the H-containing and bidentate carbonates from 300 to 100-170°C and maintains the sample in the oxidized state, which is active in subsequent CO adsorption and oxidation. CO oxidation by oxygen of the catalyst diminishes the activity of the sample in these processes and increases the decomposition temperature of the carbonate complexes. Taking into account the properties of the adsorption complexes, we concluded that the H-containing and bidentate carbonates are involved in CO oxidation by oxygen of the catalyst at ~170°C under isothermal conditions. The rate limiting step is the decomposition of the carbonates, a process whose activation energy is 65-74 kJ/mol.

Sobre autores

N. Il’ichev

Semenov Institute of Chemical Physics

Autor responsável pela correspondência
Email: Ilichev-an@mail.ru
Rússia, Moscow, 119991

Z. Fattakhova

Semenov Institute of Chemical Physics

Email: Ilichev-an@mail.ru
Rússia, Moscow, 119991

D. Shashkin

Semenov Institute of Chemical Physics

Email: Ilichev-an@mail.ru
Rússia, Moscow, 119991

V. Matyshak

Semenov Institute of Chemical Physics

Email: Ilichev-an@mail.ru
Rússia, Moscow, 119991

V. Korchak

Semenov Institute of Chemical Physics

Email: Ilichev-an@mail.ru
Rússia, Moscow, 119991

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