Palladium hydrogenation catalyst based on a porous carbon material obtained upon the dehydrochlorination of a chloro polymer


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The applicability of a porous carbon material obtained as a result of the “chemical” dehydrochlorination of chlorinated polyvinyl chloride as a support for palladium hydrogenation catalysts was demonstrated. The efficiency of the catalyst was evaluated in the liquid-phase reactions of nitrobenzene hydrogenation and chlorobenzene hydrodechlorination. Although the specific activity of the catalyst was lower by a factor of 3–4 than that of the samples based on Sibunit and carbon nanotubes, the complete conversion of the initial compounds with the selective formation of end products under mild conditions was achieved at a relatively low palladium content (1.5%).

作者简介

R. Mironenko

Institute of Hydrocarbons Processing, Siberian Branch; Dostoevsky Omsk State University

编辑信件的主要联系方式.
Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644077

O. Belskaya

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University

Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644050

V. Solodovnichenko

Institute of Hydrocarbons Processing, Siberian Branch; Omsk Scientific Center, Siberian Branch

Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644024

T. Gulyaeva

Institute of Hydrocarbons Processing, Siberian Branch

Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040

Yu. Kryazhev

Institute of Hydrocarbons Processing, Siberian Branch; Omsk Scientific Center, Siberian Branch

Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644024

V. Likholobov

Institute of Hydrocarbons Processing, Siberian Branch; Omsk Scientific Center, Siberian Branch

Email: ch-mrm@mail.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644024

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