Email this article Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate
- Authors: Durakov S.A.1, Shamsiev R.S.1, Flid V.R.1, Gekhman A.E.2
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Affiliations:
- MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 60, No 3 (2019)
- Pages: 245-249
- Section: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/164233
- DOI: https://doi.org/10.1134/S0023158419030042
- ID: 164233
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Abstract
Norbornadiene allylation by allyl formate in the presence of palladium catalytic systems has a number of features associated with different directions of β-hydride transfer in key intermediates, which can be carried out with the participation of allyl, norbornenyl, or formyl fragments. The value of the kinetic isotope effect and the nature of the limiting step in the reaction of hydroallylation of norbornadiene are determined using deuterated reagents.
About the authors
S. A. Durakov
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Email: vitaly-flid@yandex.ru
Russian Federation, Moscow, 119571
R. S. Shamsiev
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Email: vitaly-flid@yandex.ru
Russian Federation, Moscow, 119571
V. R. Flid
MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Author for correspondence.
Email: vitaly-flid@yandex.ru
Russian Federation, Moscow, 119571
A. E. Gekhman
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: vitaly-flid@yandex.ru
Russian Federation, Moscow, 119991
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