Carbon Deposits Formed on the Surface of Ru–Ni Catalysts During the Mixed Reforming of Methane Process

Abstract

Monometallic nickel and bimetallic ruthenium–nickel catalysts supported onto aluminum oxide without additives and aluminum oxide modified with MgO and CaO were prepared by an impregnation method. The catalysts were tested in the process of the mixed reforming of methane, and their properties were characterized by thermogravimetry, scanning electron microscopy, and X-ray diffractometry. The total organic carbon content of the catalysts was also measured. The promoting effect of ruthenium and structural promoters on the catalytic activity of Ni/Al₂O₃ was confirmed. The Ru–Ni/MgO–Al₂O₃ catalyst exhibited the highest stability and activity; this fact can be explained by the increased adsorption of methane on the surface of ruthenium–nickel clusters.