Отправить статью по E-mail Palladium–Ruthenium Catalyst for Selective Hydrogenation of Furfural to Cyclopentanol
- Авторы: Mironenko R.M.1,2, Belskaya O.B.1,3, Lavrenov A.V.1, Likholobov V.A.1,3,4
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Учреждения:
- Institute of Hydrocarbons Processing, Siberian Branch
- Dostoevsky Omsk State University
- Omsk State Technical University
- Omsk Scientific Center, Siberian Branch
- Выпуск: Том 59, № 3 (2018)
- Страницы: 339-346
- Раздел: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/163802
- DOI: https://doi.org/10.1134/S0023158418030151
- ID: 163802
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Аннотация
Bimetallic Pd–Ru/C catalyst was shown to be much more active in the aqueous-phase hydrogenation of furfural (473 K, 8 MPa) in comparison with both Pd/C and Ru/C catalysts. The enhanced hydrogenation activity manifested itself as an increased yield of cyclopentanol (77%) at a complete conversion of furfural. The observed synergistic effect between palladium and ruthenium in the tested reaction can be related to changes in the electronic state and particle size of supported metals upon interaction with each other and the Pd–Ru alloy formation.
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R. Mironenko
Institute of Hydrocarbons Processing, Siberian Branch; Dostoevsky Omsk State University
Автор, ответственный за переписку.
Email: mironenko@ihcp.ru
Россия, Omsk, 644040; Omsk, 644077
O. Belskaya
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University
Email: mironenko@ihcp.ru
Россия, Omsk, 644040; Omsk, 644050
A. Lavrenov
Institute of Hydrocarbons Processing, Siberian Branch
Email: mironenko@ihcp.ru
Россия, Omsk, 644040
V. Likholobov
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University; Omsk Scientific Center, Siberian Branch
Email: mironenko@ihcp.ru
Россия, Omsk, 644040; Omsk, 644050; Omsk, 644024
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