Effect of the nature of the active-component precursor on the properties of Pt/MgAlOx catalysts in propane and n-decane dehydrogenation
- Authors: Stepanova L.N.1,2, Belskaya O.B.1,3, Likholobov V.A.1,3,4
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Affiliations:
- Institute of Hydrocarbons Processing, Siberian Branch
- Omsk State University
- Omsk State Technical University
- Omsk Research Center, Siberian Branch
- Issue: Vol 58, No 4 (2017)
- Pages: 383-391
- Section: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/163098
- DOI: https://doi.org/10.1134/S0023158417040188
- ID: 163098
Cite item
Abstract
The Pt/MgAlOx catalysts, in which a mixed aluminum–magnesium oxide obtained by the heat treatment of corresponding layered double hydroxides was used as a support, were studied. The effects of the nature of active-component precursors ([PtCl6]2–, [PtCl4]2–, and [Pt3(CO)6]62-), and the Mg/Al ratio in the support on the anchoring of complexes, the disperse state of platinum, and the properties of the obtained catalysts in the reactions of propane and n-decane dehydrogenation were found.
About the authors
L. N. Stepanova
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State University
Author for correspondence.
Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644077
O. B. Belskaya
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University
Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644050
V. A. Likholobov
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University; Omsk Research Center, Siberian Branch
Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644050; Omsk, 644024
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