Effect of the nature of the active-component precursor on the properties of Pt/MgAlOx catalysts in propane and n-decane dehydrogenation


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Abstract

The Pt/MgAlOx catalysts, in which a mixed aluminum–magnesium oxide obtained by the heat treatment of corresponding layered double hydroxides was used as a support, were studied. The effects of the nature of active-component precursors ([PtCl6]2–, [PtCl4]2–, and [Pt3(CO)6]62-), and the Mg/Al ratio in the support on the anchoring of complexes, the disperse state of platinum, and the properties of the obtained catalysts in the reactions of propane and n-decane dehydrogenation were found.

About the authors

L. N. Stepanova

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State University

Author for correspondence.
Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644077

O. B. Belskaya

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University

Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644050

V. A. Likholobov

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University; Omsk Research Center, Siberian Branch

Email: Lchem@yandex.ru
Russian Federation, Omsk, 644040; Omsk, 644050; Omsk, 644024

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