Saturation kinetics and relative reactivity of the double bonds of alicyclic dienes in their hydrogenation

详细

The kinetics of the liquid-phase hydrogenation of cyclodienes with various structures (endo-tricyclo[ 5.2.1.0^2,6]decadiene-3,8 and cis,cis-1,5-cyclooctadiene) by hydrogen over a finely dispersed 1%Pd/C catalyst at atmospheric pressure has been studied. The catalyst provides the possibility for successive saturation of the double bonds of the dienes. The reactivities of the cyclodienes determined by their electron-donating properties have been compared. The solvent nature is the determining factor in the ratio of hydrogen absorption rates in the case of successive saturation of the double bonds of the hydrocarbons. The hydrogenation kinetics of cyclic dienes, including dicyclopentadiene, can be modeled using the Langmuir–Hinshelwood equation when the process is carried out in a perfectly mixed flow reactor.