Industrial catalyst for the selective Fischer–Tropsch synthesis of long-chain hydrocarbons


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The results of development of an industrial supported cobalt–silica gel catalyst for the Fischer–Tropsch synthesis are reported. The studies included the selection of a support and the determination of an optimum active component content, a calcination temperature, and the effect of doping with aluminum oxide on the physicochemical and catalytic properties of the Co–SiO2 system. The catalyst samples were characterized by a set of physicochemical methods. The on-stream stability of the supported cobalt–silica gel catalyst was tested in the continuous mode for 1000 h. In the course of the entire test cycle, the catalyst exhibited stable operation under varied synthesis temperature and gas space velocity, and it can be recommended for industrial applications. The experimental results were used for the preparation of a pilot batch of the catalyst.

作者简介

S. Mitchenko

Platov South-Russian State Polytechnic University (NPI); Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128; Donetsk, 83114

A. Savost’yanov

Platov South-Russian State Polytechnic University (NPI)

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

R. Yakovenko

Platov South-Russian State Polytechnic University (NPI)

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

G. Narochnyi

Platov South-Russian State Polytechnic University (NPI)

编辑信件的主要联系方式.
Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

V. Bakun

Platov South-Russian State Polytechnic University (NPI)

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

S. Sulima

Platov South-Russian State Polytechnic University (NPI)

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

E. Yakuba

Platov South-Russian State Polytechnic University (NPI)

Email: narochgb@bk.ru
俄罗斯联邦, Novocherkassk, Rostov oblast, 346128

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