Email this article Kinetics of n-propylmercaptan oxidation by cobalt(III) octahydroxyphthalocyanine in an alkali medium
- Authors: Ziyadova T.M.1, Burmistrov V.A.1,2, Maizlish V.E.1, Koifman O.I.1,2
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Affiliations:
- Research Institute of Macroheterocyclic Compounds
- Krestov Institute of Solution Chemistry
- Issue: Vol 57, No 3 (2016)
- Pages: 313-318
- Section: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/162425
- DOI: https://doi.org/10.1134/S0023158416030186
- ID: 162425
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Abstract
The specific features of the association of cobalt octahydroxyphthalocyanine in aqueous alkaline solutions have been investigated by electron spectroscopy. The kinetic parameters of the oxidation of n-propylmercaptan by the phthalocyanine complex of cobalt in the absence of oxygen have been determined. The association leads to a decrease in the activity of the complex and to changes in activation parameters.
About the authors
T. M. Ziyadova
Research Institute of Macroheterocyclic Compounds
Author for correspondence.
Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000
V. A. Burmistrov
Research Institute of Macroheterocyclic Compounds; Krestov Institute of Solution Chemistry
Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000; Ivanovo, 153045
V. E. Maizlish
Research Institute of Macroheterocyclic Compounds
Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000
O. I. Koifman
Research Institute of Macroheterocyclic Compounds; Krestov Institute of Solution Chemistry
Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000; Ivanovo, 153045
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