Kinetics of n-propylmercaptan oxidation by cobalt(III) octahydroxyphthalocyanine in an alkali medium


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Abstract

The specific features of the association of cobalt octahydroxyphthalocyanine in aqueous alkaline solutions have been investigated by electron spectroscopy. The kinetic parameters of the oxidation of n-propylmercaptan by the phthalocyanine complex of cobalt in the absence of oxygen have been determined. The association leads to a decrease in the activity of the complex and to changes in activation parameters.

About the authors

T. M. Ziyadova

Research Institute of Macroheterocyclic Compounds

Author for correspondence.
Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000

V. A. Burmistrov

Research Institute of Macroheterocyclic Compounds; Krestov Institute of Solution Chemistry

Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000; Ivanovo, 153045

V. E. Maizlish

Research Institute of Macroheterocyclic Compounds

Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000

O. I. Koifman

Research Institute of Macroheterocyclic Compounds; Krestov Institute of Solution Chemistry

Email: ziyadova_tm@mail.ru
Russian Federation, Ivanovo, 153000; Ivanovo, 153045

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