Kinetic description of the hydrogenation of nitrobenzene and nitrosobenzene on skeletal nickel in aqueous solutions of propan-2-ol of different compositions
- Authors: Romanenko Y.E.1, Merkin A.A.1, Lefedova O.V.1
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Affiliations:
- Research Institute of Thermodynamics and Kinetics of Chemical Processes
- Issue: Vol 57, No 2 (2016)
- Pages: 212-218
- Section: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/162398
- DOI: https://doi.org/10.1134/S0023158416020117
- ID: 162398
Cite item
Abstract
The kinetics of the hydrogenation of nitrosobenzene and nitrobenzene is simulated taking into account accompanying processes and specific features of the conversion of reactive groups. The constants of the hypothetical reaction steps are calculated. The influence of sodium hydroxide and acetic acid on the kinetic parameters of the reactions is discussed.
About the authors
Yu. E. Romanenko
Research Institute of Thermodynamics and Kinetics of Chemical Processes
Author for correspondence.
Email: Romanenko@isuct.ru
Russian Federation, Ivanovo, 153000
A. A. Merkin
Research Institute of Thermodynamics and Kinetics of Chemical Processes
Email: physchem@isuct.ru
Russian Federation, Ivanovo, 153000
O. V. Lefedova
Research Institute of Thermodynamics and Kinetics of Chemical Processes
Author for correspondence.
Email: physchem@isuct.ru
Russian Federation, Ivanovo, 153000
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