Kinetic description of the hydrogenation of nitrobenzene and nitrosobenzene on skeletal nickel in aqueous solutions of propan-2-ol of different compositions


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Abstract

The kinetics of the hydrogenation of nitrosobenzene and nitrobenzene is simulated taking into account accompanying processes and specific features of the conversion of reactive groups. The constants of the hypothetical reaction steps are calculated. The influence of sodium hydroxide and acetic acid on the kinetic parameters of the reactions is discussed.

About the authors

Yu. E. Romanenko

Research Institute of Thermodynamics and Kinetics of Chemical Processes

Author for correspondence.
Email: Romanenko@isuct.ru
Russian Federation, Ivanovo, 153000

A. A. Merkin

Research Institute of Thermodynamics and Kinetics of Chemical Processes

Email: physchem@isuct.ru
Russian Federation, Ivanovo, 153000

O. V. Lefedova

Research Institute of Thermodynamics and Kinetics of Chemical Processes

Author for correspondence.
Email: physchem@isuct.ru
Russian Federation, Ivanovo, 153000

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