Composition and Structure of the Asphaltene Components of Bituminous Oils
- Authors: Kovalenko E.Y.1, Sagachenko T.A.1, Min R.S.1, Ogorodnikov V.D.1, Perevezentsev S.A.1
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Affiliations:
- Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
- Issue: No 2-3 (2023)
- Pages: 35-40
- Section: Articles
- URL: https://journals.rcsi.science/0023-1177/article/view/140048
- DOI: https://doi.org/10.31857/S0023117723020081
- EDN: https://elibrary.ru/BGZXGK
- ID: 140048
Cite item
Abstract
It was shown that the averaged asphaltene molecules of bituminous oils include no more than four structural blocks, the skeletons of which differ in the numbers of aromatic and naphthenic rings and the numbers of carbon atoms in alkyl substituents. The crystalline part of the macromolecules of the test asphaltenes had a layered structure. In terms of the number of layers of a packed structure, the thickness and the average diameter of its packing, and the number of aromatic rings in a layer, the test asphaltenes differed insignificantly.
About the authors
E. Yu. Kovalenko
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: kovalenko@ipc.tsc.ru
Tomsk, 634055 Russia
T. A. Sagachenko
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: dissovet@ipc.tsc.ru
Tomsk, 634055 Russia
R. S. Min
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: rsm@ipc.tsc.ru
Tomsk, 634055 Russia
V. D. Ogorodnikov
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: ogorodvd@ipc.tsc.ru
Tomsk, 634055 Russia
S. A. Perevezentsev
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: slay@ipc.tsc.ru
Tomsk, 634055 Russia
References
- Кадиев Х.М., Зайцева О.В., Магомадов Э.Э., Чернышева Е.А., Окнина Н.В., Батов А.Е., Кадиева М.Х., Капустин В.М., Хаджиев С.Н. // Нефтехимия. 2015. Т. 55. № 4. С. 337. [Petroleum Chemistry, 2015, vol. 55, no. 6, p. 487. https://doi.org/10.1134/S0965544115060067].https://doi.org/10.7868/S0028242115040061
- Zuo P., Qu S., Shen W. // J. Energy Chem. 2019. V. 34. P. 186. https://doi.org/10.1016/j.jechem.2018.10.004
- Peng P., Morales-Izquierdo A., Hogg A., Strauaz O.P. // Energy Fuels. 1997. V. 11. No. 6. P. 1171. https://doi.org/10.1021/ef970027c
- Cheshkova T.V., Sergun V.P., Kovalenko E.Y., Gerasimova N.N., Sagachenko T.A., Min R.S. // Energy Fuels. 2019. V. 33. No. 9. P. 7971. https://doi.org/10.1021/acs.energyfuels.9b00285
- Kayukova G.P., Gubaidullin A.T., Romanov G.V., Petrov S.M., Vakhin A.V., Petrukhina N.N. // Energy Fuels. 2016. V. 30. No. 2. P. 773. https://doi.org/10.1021/acs.energyfuels.5b01328
- Созинов С.А., Сотникова Л.В., Попова А.Н., Хицова Л.М., Колмыков Р.П., Малышева В.Ю., Лырщиков С.Ю., Краснов С.А., Исмагилов З.Р. // Химия в интересах устойчивого развития. 2018. Т. 26. № 6. С. 603. https://doi.org/10.15372/KhUR20180606
- Антипенко В.Р., Федяева О.Н., Востриков А.А. // Нефтехимия. 2021. Т. 61. № 4. С. 547. [Petroleum Chemistry, 2021, vol. 61, no. 7, p. 787. https://doi.org/10.1134/S0965544121070069].https://doi.org/10.31857/S0028242121040109
- Уразов Х.Х., Свириденко Н.Н. // ХТТ. 2022. № 2. С. 46. [Solid Fuel Chemistry, 2022, vol. 56, no. 2, p. 128. https://doi.org/10.3103/S0361521922020100].https://doi.org/10.31857/S0023117722020104
- Antipenko V.R., Fedyaeva O.N., Vostrikov A.A., Grin’ko A.A. // Petroleum Chemistry, 2020. V. 60. No. 6. P. 668. https://doi.org/10.1134/S096554412006002X
- Камьянов В.Ф., Большаков Г.Ф. // Нефтехимия. 1984. Т. 24. № 4. С. 450.
- Yen T.F., Erdman J.G., Pollack S.S. // Anal. Chem., 1961, vol. 33, p. 1587. https://doi.org/10.1021/ac60179a039
- Dickie J.P., Yen T.F. // Anal. Chem., 1967, vol. 39, p. 1847. https://doi.org/10.1021/ac50157a057
- Камьянов В.Ф., Бодрая Н.В., Сивирилов П.П., Унгер Ф.Г., Филимонова Т.А., Чернявский В.Н. // Нефтехимия. 1989. Т. 29. № 1. С. 3. [Petroleum Chemistry U.S.S.R., 1989, vol. 29, no. 1, p. 1. https://doi.org/10.1016/0031-6458(89)90001-4].
- Дмитриев Д.Е., Головко А.К. Свидетельство о государственной регистрации программы для ЭВМ QMR № 2010612415 от 06.04.10 г.