Thermolysis of Brown Coal in Water in the Presence of a Catalytic Additive Based on Iron Oxides
- Authors: Kopytov M.A.1, Boyar S.V.1
-
Affiliations:
- Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
- Issue: No 2-3 (2023)
- Pages: 16-19
- Section: Articles
- URL: https://journals.rcsi.science/0023-1177/article/view/140041
- DOI: https://doi.org/10.31857/S0023117723020068
- EDN: https://elibrary.ru/BFVUSG
- ID: 140041
Cite item
Abstract
The thermolysis of brown coal was carried out at temperatures of 360 and 380°C in water without a catalytic additive and in the presence of a catalyst based on iron oxides, and the composition of the products was studied. It was shown that the use of a catalytic additive in the course of the thermolysis of coal in water led to an increase in the yield of liquid and gaseous hydrocarbons; in this case, the fraction of maltenes in liquid products increased, and the concentrations of hydrogen and carbon oxides in gaseous products increased significantly.
Keywords
About the authors
M. A. Kopytov
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Email: kma@ipc.tsc.ru
Tomsk, 634055 Russia
S. V. Boyar
Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: bsv@ipc.tsc.ru
Tomsk, 634055 Russia
References
- Ashida R., Morimoto M., Makino Y., Umemoto S., Nakagawa H., Miura K., Saito K., Kato K. // Fuel. 2009. V. 88. № 8. P. 1485.
- Li C.Z. // Fuel. 2007. V. 86. № 12–13. P. 1664.
- Fedyaeva O.N., Vostrikov A.A., Shishkin A.V., Sokol M.Ya., Fedorova N.I., Kashirtsev V.A. // J. Supercrit. Fluids. 2012. V. 62. P. 155.
- Sakaguchi M., Laursen K., Nakagawa H., Miura K. // Fuel Process. Technol. 2008. V. 89. № 4. P. 391.
- Morimoto M., Nakagawa H., Miura K. // Energy and Fuels. 2010. V. 24. № 5. P. 3060.
- Wang Z., Shui H., Pei Z., Gao J. // Fuel. 2008. V. 87. № 4–5. P. 527.
- Zeng C., Favas G., Wu H., Chaffee A.L., Hayashi J., Li C.-Z. // Energy and Fuels. 2006. V. 20. № 1. P. 281.
- Zeng C., Clayton S., Wu H., Hayashi J., Li C.-Z. // Energy and Fuels. 2007. V. 21. № 2. P. 399.
- Копытов М.А., Головко А.К. // ХТТ. 2013. № 6. С. 59. [Solid Fuel Chemistry, 2013, vol. 47, no. 6, p. 370. https://doi.org/10.3103/S0361521913060049]https://doi.org/10.7868/S0023117713060042
- Нальгиева Х.В., Копытов М.А., Чешкова Т.В., Кривцов Е.Б., Мамонтов Г.В. // Нефть. Газ. Новации. 2021. № 6. С. 13.
- Липович В.Г., Калабин Г.А., Калечиц И.В. Химия и переработка угля. М.: Химия, 1988. 336 с.
- Головко А.К., Копытов М.А., Шаронова О.М., Кирик Н.П., Аншиц А.Г. // Катализ в промышленности. 2015. № 4. С. 65. [Catalysis in Industry. 2015, vol. 7, no. 4, p. 293. https://doi.org/10.1134/S2070050415040078]
- Камьянов В.Ф. Химический состав нефтей Западной Сибири. Новосибирск: Наука, 1988. 288 с.