A family of crystal structures with [Pb3(OH)4Co(NO2)3]2+ cations


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详细

The structure of two crystalline modifications of [Pb3(OH)4Co(NO2)3](NO2)2 containing tetrahedral [Pb3(OH)4Co(NO2)3]2+ complex cations is studied. Three lead atoms and one cobalt atom are located in the vertices of a distorted tetrahedron with the edges of 3.39-3.92 Å. The distances from the metal atoms to the oxygen atoms belonging to μ3 bridging hydroxo groups are within 1.910-1.956 Å for Co–O and 2.340-2.439 Å for Pb–O. The packing motifs of the crystal structures are analyzed.

作者简介

S. Khranenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk

N. Kuratieva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University

Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

S. Gromilov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University

编辑信件的主要联系方式.
Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

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