Email this article A family of crystal structures with [Pb3(OH)4Co(NO2)3]2+ cations
- Authors: Khranenko S.P.1, Kuratieva N.V.1,2, Gromilov S.A.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 57, No 5 (2016)
- Pages: 1044-1048
- Section: Brief Communications
- URL: https://journals.rcsi.science/0022-4766/article/view/160318
- DOI: https://doi.org/10.1134/S0022476616050292
- ID: 160318
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Abstract
The structure of two crystalline modifications of [Pb3(OH)4Co(NO2)3](NO2)2 containing tetrahedral [Pb3(OH)4Co(NO2)3]2+ complex cations is studied. Three lead atoms and one cobalt atom are located in the vertices of a distorted tetrahedron with the edges of 3.39-3.92 Å. The distances from the metal atoms to the oxygen atoms belonging to μ3 bridging hydroxo groups are within 1.910-1.956 Å for Co–O and 2.340-2.439 Å for Pb–O. The packing motifs of the crystal structures are analyzed.
About the authors
S. P. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. A. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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