Отправить статью по E-mail Nickel(II) complexes with cytosine and threonine: Synthesis and structure
- Авторы: Pugachev D.V.1, Esina N.Y.1, Kurasova M.N.1, Fortalnova E.A.1, Venskovskii N.U.1, Lazarenko V.A.2, Trigub A.L.2, Khrustalev V.N.1
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Учреждения:
- People’s Friendship University of Russia
- National Research Center “Kurchatov Institute”
- Выпуск: Том 58, № 7 (2017)
- Страницы: 1318-1323
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161613
- DOI: https://doi.org/10.1134/S0022476617070071
- ID: 161613
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Аннотация
Mono-and mixed-ligand complexes with the composition [Ni(Cyt)2(H2O)2]Cl2, [Ni(Thr–)2(H2O)2] and [Ni(Thr–)(Cyt)(H2O)2]Cl are synthesized and studied. Using IR spectroscopy it is determined that in the complex compounds, cytosine is bidentate (C=O group oxygen and heterocycle N3), threonine interacts with the Ni(II) ion due to amino and carboxyl groups. The models of the atomic structure of the studied compounds are proposed based on the EXAFS and XANES spectroscopy results.
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D. Pugachev
People’s Friendship University of Russia
Автор, ответственный за переписку.
Email: dmpugachev@mail.ru
Россия, Moscow
N. Esina
People’s Friendship University of Russia
Email: dmpugachev@mail.ru
Россия, Moscow
M. Kurasova
People’s Friendship University of Russia
Email: dmpugachev@mail.ru
Россия, Moscow
E. Fortalnova
People’s Friendship University of Russia
Email: dmpugachev@mail.ru
Россия, Moscow
N. Venskovskii
People’s Friendship University of Russia
Email: dmpugachev@mail.ru
Россия, Moscow
V. Lazarenko
National Research Center “Kurchatov Institute”
Email: dmpugachev@mail.ru
Россия, Moscow
A. Trigub
National Research Center “Kurchatov Institute”
Email: dmpugachev@mail.ru
Россия, Moscow
V. Khrustalev
People’s Friendship University of Russia
Email: dmpugachev@mail.ru
Россия, Moscow
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